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Some aspects of the reactivity of RCu/BF3 reagents towards the ether linkage

Authors
Mangeney, Pierre
Ghribi, A.
Jachiet, D.
Normant, Jean F.
Holmes, A.B.
Published in Philosophical Transactions. A, Mathematical, Physical and Engineering Sciences. 1988, vol. 326, no. 1592, p. 557-564
Abstract Organocopper reagents associated with a strong Lewis acid such as BF$_{3}$ react with the C--O single bond of orthoesters, acetals and epoxides. The diastereoselective cleavage of chiral acetals opens a new way of obtaining chiral secondary alcohols or chiral
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ALEXAKIS, Alexandre et al. Some aspects of the reactivity of RCu/BF3 reagents towards the ether linkage. In: Philosophical Transactions. A, Mathematical, Physical and Engineering Sciences, 1988, vol. 326, n° 1592, p. 557-564. https://archive-ouverte.unige.ch/unige:8226

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Deposited on : 2010-06-21

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