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Scientific article
English

Some aspects of the reactivity of RCu/BF3 reagents towards the ether linkage

Publication date1988
Abstract

Organocopper reagents associated with a strong Lewis acid such as BF$_{3}$ react with the C--O single bond of orthoesters, acetals and epoxides. The diastereoselective cleavage of chiral acetals opens a new way of obtaining chiral secondary alcohols or chiral

Affiliation Not a UNIGE publication
Citation (ISO format)
ALEXAKIS, Alexandre et al. Some aspects of the reactivity of RCu/BF3 reagents towards the ether linkage. In: Philosophical transactions - Royal Society. Mathematical, Physical and engineering sciences, 1988, vol. 326, n° 1592, p. 557–564. doi: 10.1098/rsta.1988.0106
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ISSN of the journal1364-503X
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