Some aspects of the reactivity of RCu/BF3 reagents towards the ether linkage

Alexakis, Alexandre; Mangeney, Pierre; Ghribi, A.; Jachiet, D.; Normant, Jean F.; Holmes, A.B.

doi:10.1098/rsta.1988.0106

Scientific article

English

Some aspects of the reactivity of RCu/BF3 reagents towards the ether linkage

ContributorsAlexakis, Alexandre; Mangeney, Pierre; Ghribi, A.; Jachiet, D.; Normant, Jean F.; Holmes, A.B.

Published inPhilosophical transactions - Royal Society. Mathematical, Physical and engineering sciences, vol. 326, no. 1592, p. 557-564

Publication date1988

Abstract

Organocopper reagents associated with a strong Lewis acid such as BF$_{3}$ react with the C--O single bond of orthoesters, acetals and epoxides. The diastereoselective cleavage of chiral acetals opens a new way of obtaining chiral secondary alcohols or chiral

Affiliation Not a UNIGE publication

Citation (ISO format)

ALEXAKIS, Alexandre et al. Some aspects of the reactivity of RCu/BF3 reagents towards the ether linkage. In: Philosophical transactions - Royal Society. Mathematical, Physical and engineering sciences, 1988, vol. 326, n° 1592, p. 557–564. doi: 10.1098/rsta.1988.0106

Article (Published version)

Identifiers

PID : unige:8226
DOI : 10.1098/rsta.1988.0106

ISSN of the journal1364-503X

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Some aspects of the reactivity of RCu/BF3 reagents towards the ether linkage

Organocopper reagents associated with a strong Lewis acid such as BF$_{3}$ react with the C--O single bond of orthoesters, acetals and epoxides. The diastereoselective cleavage of chiral acetals opens a new way of obtaining chiral secondary alcohols or chiral

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