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Scientific article
English

A completely stereoselective intramolecular Diels-Alder reaction in the substituted cyclohexanol series

Published inTetrahedron, vol. 45, no. 19, p. 6203-6210
Publication date1989
Abstract

Subtituted dienyl cyclohexanols, obtained through opening of cyclohexene oxide by dienyl aluminum reagents, are easily esterified with acryloyl, crotonyl or methacryoyl chloride or with maleic anhydride. These esters undergo a completely stereoselective Lewis acid catalyzed Diesels-Alder reaction. The obtained product were characterized by X-ray crystallography.

Affiliation Not a UNIGE publication
Citation (ISO format)
ALEXAKIS, Alexandre, JACHIET, D. A completely stereoselective intramolecular Diels-Alder reaction in the substituted cyclohexanol series. In: Tetrahedron, 1989, vol. 45, n° 19, p. 6203–6210. doi: 10.1016/S0040-4020(01)85131-0
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ISSN of the journal0040-4020
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