A completely stereoselective intramolecular Diels-Alder reaction in the substituted cyclohexanol series

Alexakis, Alexandre; Jachiet, D.

doi:10.1016/S0040-4020(01)85131-0

Scientific article

English

A completely stereoselective intramolecular Diels-Alder reaction in the substituted cyclohexanol series

ContributorsAlexakis, Alexandre; Jachiet, D.

Published inTetrahedron, vol. 45, no. 19, p. 6203-6210

Publication date1989

Abstract

Subtituted dienyl cyclohexanols, obtained through opening of cyclohexene oxide by dienyl aluminum reagents, are easily esterified with acryloyl, crotonyl or methacryoyl chloride or with maleic anhydride. These esters undergo a completely stereoselective Lewis acid catalyzed Diesels-Alder reaction. The obtained product were characterized by X-ray crystallography.

Affiliation entities

Not a UNIGE publication

Citation (ISO format)

ALEXAKIS, Alexandre, JACHIET, D. A completely stereoselective intramolecular Diels-Alder reaction in the substituted cyclohexanol series. In: Tetrahedron, 1989, vol. 45, n° 19, p. 6203–6210. doi: 10.1016/S0040-4020(01)85131-0

Article (Published version)

Identifiers

PID : unige:8172
DOI : 10.1016/S0040-4020(01)85131-0

Journal ISSN0040-4020

519views

0downloads

Creation21/06/2010 14:44:25

First validation21/06/2010 14:44:25

Update time14/03/2023 15:48:25

Status update14/03/2023 15:48:25

Last indexation29/10/2024 15:34:15

Archive ouverte UNIGE

A completely stereoselective intramolecular Diels-Alder reaction in the substituted cyclohexanol series

Technical informations