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Enantioselective one-pot organocatalytic michael addition/gold-catalyzed tandem acetalization/cyclization |
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Published in | Angewandte Chemie. 2009, vol. 48, no. 47, p. 8923-8926 | |
Abstract | A one-pot process consisting of a Michael addition to a nitroenyne and a subsequent acetalization/cyclization is reported (see scheme; TMS=trimethylsilyl), which results in the formation of nitro-substituted tetrahydrofuranyl ethers with high diastereo- and enantioselectivities. Organocatalysis and gold catalysis are compatible and complementary in a one-pot process. | |
Identifiers | PMID: 19847839 | |
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Citation (ISO format) | BELOT, Sebastian Pascal et al. Enantioselective one-pot organocatalytic michael addition/gold-catalyzed tandem acetalization/cyclization. In: Angewandte Chemie, 2009, vol. 48, n° 47, p. 8923-8926. doi: 10.1002/anie.200903905 https://archive-ouverte.unige.ch/unige:8103 |