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Title

Enantioselective one-pot organocatalytic michael addition/gold-catalyzed tandem acetalization/cyclization

Authors
Vogt, Kim A.
Krause, Norbert
Published in Angewandte Chemie: International Edition. 2009, vol. 48, no. 47, p. 8923-8926
Abstract A one-pot process consisting of a Michael addition to a nitroenyne and a subsequent acetalization/cyclization is reported (see scheme; TMS=trimethylsilyl), which results in the formation of nitro-substituted tetrahydrofuranyl ethers with high diastereo- and enantioselectivities. Organocatalysis and gold catalysis are compatible and complementary in a one-pot process.
Identifiers
PMID: 19847839
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BELOT, Sebastian Pascal et al. Enantioselective one-pot organocatalytic michael addition/gold-catalyzed tandem acetalization/cyclization. In: Angewandte Chemie: International Edition, 2009, vol. 48, n° 47, p. 8923-8926. https://archive-ouverte.unige.ch/unige:8103

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Deposited on : 2010-06-21

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