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Diamine-catalyzed asymmetric Michael additions of aldehydes and ketones to nitrostyrene

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Published in Organic Letters. 2002, vol. 4, no. 21, p. 3611-3614
Abstract The direct Michael addition of aldehydes and ketones to nitrostyrene, catalyzed by N-i-Pr-2,2'-bipyrrolidine, is described. The desired 1,4-adducts are obtained in excellent yield with enantioselectivities up to 85% ee and dr up to 95:5 of the syn product.
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PMID: 12375900
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ALEXAKIS, Alexandre, ANDREY, Olivier. Diamine-catalyzed asymmetric Michael additions of aldehydes and ketones to nitrostyrene. In: Organic Letters, 2002, vol. 4, n° 21, p. 3611-3614. https://archive-ouverte.unige.ch/unige:8036

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Deposited on : 2010-06-21

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