UNIGE document Scientific Article
previous document  unige:8016  next document
add to browser collection
Title

1,4-Dichloro- and 1,4-Dibromo-2-butenes as Substrate for Cu-catalyzed Asymmetric Allylic Substitution

Authors
Published in Angewandte Chemie: International Edition. 2007, vol. 46, no. 15, p. 2619-2622
Abstract Cu at the AAA meeting: Difunctionalized allylic substrates can undergo Cu-catalyzed asymmetric allylic alkylation (AAA) reactions with high enantioselectivities. The products have a functional group that remains for further transformation through substitution with a nucleophile (Nu) or electrophile (E) with conservation of optical purity (see scheme; TC=thiophene carboxylate).
Keywords AlkylationAllylic compoundsAsymmetric catalysisCopperNucleophilic substitution
Identifiers
PMID: 17348048
Full text
Article (Published version) - document accessible for UNIGE members only Limited access to UNIGE
Structures
Citation
(ISO format)
FALCIOLA, Caroline Alexandra, ALEXAKIS, Alexandre. 1,4-Dichloro- and 1,4-Dibromo-2-butenes as Substrate for Cu-catalyzed Asymmetric Allylic Substitution. In: Angewandte Chemie: International Edition, 2007, vol. 46, n° 15, p. 2619-2622. https://archive-ouverte.unige.ch/unige:8016

337 hits

30 downloads

Update

Deposited on : 2010-06-21

Export document
Format :
Citation style :