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Asymmetric bromine–lithium exchange: on the importance of both the diamine ligand and the organolithium reagent

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Published in Chemical Communications. 2015, vol. 51, no. 95, p. 16912-16915
Abstract The asymmetric bromine–lithium exchange on a series of prochiral biphenyls was investigated. As in many asymmetric organolithium reactions, the chiral ligand (here a diamine) was considered to be the enantiocontrolling element. We show here that the organolithium reagent also plays an important role.
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Other version: http://xlink.rsc.org/?DOI=C5CC06548H
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Research group Groupe Alexakis
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PRAZ, Jezabel et al. Asymmetric bromine–lithium exchange: on the importance of both the diamine ligand and the organolithium reagent. In: Chemical Communications, 2015, vol. 51, n° 95, p. 16912-16915. https://archive-ouverte.unige.ch/unige:77587

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Deposited on : 2015-11-23

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