Asymmetric bromine–lithium exchange: on the importance of both the diamine ligand and the organolithium reagent

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Title		Asymmetric bromine–lithium exchange: on the importance of both the diamine ligand and the organolithium reagent
Authors		Praz, Jezabel Graff, Julien Egger, Leo Guenee, Laure Wagschal, Simon Albert Kundig, Ernst Peter Alexakis, Alexandre
Published in		Chemical Communications. 2015, vol. 51, no. 95, p. 16912-16915
Abstract		The asymmetric bromine–lithium exchange on a series of prochiral biphenyls was investigated. As in many asymmetric organolithium reactions, the chiral ligand (here a diamine) was considered to be the enantiocontrolling element. We show here that the organolithium reagent also plays an important role.
Identifiers		DOI: 10.1039/C5CC06548H
Full text		Article (Published version) (1.4 MB) - Limited access to UNIGE Other version: http://xlink.rsc.org/?DOI=C5CC06548H
Structures		Faculté des sciences / Section de chimie et biochimie / Département de chimie organique
Research group		Groupe Alexakis
Citation (ISO format)		PRAZ, Jezabel et al. Asymmetric bromine–lithium exchange: on the importance of both the diamine ligand and the organolithium reagent. In: Chemical Communications, 2015, vol. 51, n° 95, p. 16912-16915. doi: 10.1039/C5CC06548H https://archive-ouverte.unige.ch/unige:77587

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Deposited on : 2015-11-23

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