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Crystallochemical studies in the family of crystals Ba[7-x]Na[y]F₁₂Cl[2-z]Br[z] (x < 0.1, y < 0.2, z < 1.5)

Published inZeitschrift für anorganische und allgemeine Chemie, vol. 634, p. 1041-1044
Publication date2008
Abstract

A series of mixed crystals with general formula Ba7-xNayF12Cl2-zBrz in the ordered modification (space group P-6) has been studied by single crystal x-ray diffraction. Depending on synthesis conditions, the disorder in the channels (i.e. occupation of 0 0 z sites) can be changed. The disorder is found to be correlated with the refined Na content, and its effect on Ba-Cl(Br) bond length is discussed.

Citation (ISO format)
HAGEMANN, Hans-Rudolf et al. Crystallochemical studies in the family of crystals Ba[7-x]Na[y]F₁₂Cl[2-z]Br[z] (x &lt; 0.1, y &lt; 0.2, z &lt; 1.5). In: Zeitschrift für anorganische und allgemeine Chemie, 2008, vol. 634, p. 1041–1044. doi: 10.1002/zaac.200700594
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Creation10/29/2008 11:37:51 AM
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