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Enantioselective olefin epoxidation using homologous amine and iminium catalysts—a direct comparison

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Gonçalves, Maria-Héléna
Page, Philip C. Bulman
Published in Tetrahedron Letters. 2006, vol. 47, no. 30, p. 5297-5301
Abstract Homologous biphenyl and (diastereomeric) binaphthyl tertiary azepines and quaternary iminium salts were prepared from (+)-(S,S)-l-acetonamine. Both the amines and iminium ions behave as effective catalysts for the enantioselective epoxidation of unfunctionalized olefins (ee up to 83%).
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GONÇALVES, Maria-Héléna et al. Enantioselective olefin epoxidation using homologous amine and iminium catalysts—a direct comparison. In: Tetrahedron Letters, 2006, vol. 47, n° 30, p. 5297-5301. https://archive-ouverte.unige.ch/unige:7059

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Deposited on : 2010-06-18

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