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Scientific article
English

Mounting Freestanding Molecular Functions onto Surfaces: The Platform Approach

Contributors

Baisch, Belinda; Raffa, Diego; Jung, Ulrich; Magnussen, Olaf M.; Nicolas, Cyril Michel; Lacour, Jérôme; Kubitschke, Jens; Herges, Rainer

Published in

Journal of the American Chemical Society, vol. 131, no. 2, p. 442-443

Publication date

2009

Abstract

A modular system has been developed to mount molecules upright onto metal surfaces in a well controlled geometry. The approach is based on a reactive platform (triazatriangulenium salt) with an electrophilic center. Functional molecules are attached via C-C bond formation. The distance from the surface can be varied by a spacer, and the distance of the functional units from each other by the size of the platform. Self-assembly of the parent triazaangulenium salt as well as the functionalized platforms on Au(111) surfaces results in stable, hexagonally ordered adlayers.

UNIGE affiliation entities

Citation (ISO format)

BAISCH, Belinda et al. Mounting Freestanding Molecular Functions onto Surfaces: The Platform Approach. In: Journal of the American Chemical Society, 2009, vol. 131, n° 2, p. 442–443. doi: 10.1021/ja807923f

Main files (1)

Article

Identifiers

Journal ISSN

0002-7863
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Technical informations

Creation

18/06/2010 08:55:28

First validation

18/06/2010 08:55:28

Update

14/03/2023 15:42:24

Status update

14/03/2023 15:42:24

Last indexation

10/06/2025 21:34:58
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