C3 Vanadium(V) Amine Triphenolate Complexes: Vanadium Haloperoxidase Structural and Functional Models

Browse by...

Deposit

Highlights

More informations

Title		C3 Vanadium(V) Amine Triphenolate Complexes: Vanadium Haloperoxidase Structural and Functional Models
Authors		Mba, Miriam Pontini, Marta Lovat, Silvia Zonta, Cristiano Bernardinelli, Gérald Hugues Kundig, Ernst Peter Licini, Giulia
Published in		Inorganic Chemistry. 2008, vol. 47, no. 19, p. 8616-8618
Abstract		The C 3 vanadium(V) amine triphenolate complex 1f has been characterized as a structural and functional model of vanadium haloperoxidases. The complex catalyzes efficiently sulfoxidations at room temperature using hydrogen peroxide as the terminal oxidant, yielding the corresponding sulfoxides in quantitative yields and high selectivities (catalyst loading down to 0.01%, TONs up to 9900, and TOFs up to 8000 h (-1)) as well as bromination of 1,3,5-trimethoxybenzene (catalyst loading down to 0.05%, TONs up to 1260, and TOFs up to 220 h (-1)).
Identifiers		DOI: 10.1021/ic8015113 PMID: 18774797
Full text		Article - Limited access to UNIGE
Structures		Faculté des sciences / Section de chimie et biochimie / Département de chimie organique
Citation (ISO format)		MBA, Miriam et al. C3 Vanadium(V) Amine Triphenolate Complexes: Vanadium Haloperoxidase Structural and Functional Models. In: Inorganic chemistry, 2008, vol. 47, n° 19, p. 8616-8618. https://archive-ouverte.unige.ch/unige:7037