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Title

C3 Vanadium(V) Amine Triphenolate Complexes: Vanadium Haloperoxidase Structural and Functional Models

Authors
Mba, Miriam
Pontini, Marta
Lovat, Silvia
Zonta, Cristiano
Licini, Giulia
Published in Inorganic Chemistry. 2008, vol. 47, no. 19, p. 8616-8618
Abstract The C 3 vanadium(V) amine triphenolate complex 1f has been characterized as a structural and functional model of vanadium haloperoxidases. The complex catalyzes efficiently sulfoxidations at room temperature using hydrogen peroxide as the terminal oxidant, yielding the corresponding sulfoxides in quantitative yields and high selectivities (catalyst loading down to 0.01%, TONs up to 9900, and TOFs up to 8000 h (-1)) as well as bromination of 1,3,5-trimethoxybenzene (catalyst loading down to 0.05%, TONs up to 1260, and TOFs up to 220 h (-1)).
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PMID: 18774797
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MBA, Miriam et al. C3 Vanadium(V) Amine Triphenolate Complexes: Vanadium Haloperoxidase Structural and Functional Models. In: Inorganic chemistry, 2008, vol. 47, n° 19, p. 8616-8618. https://archive-ouverte.unige.ch/unige:7037

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Deposited on : 2010-06-18

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