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Effect of the Medium on the Oxaziridinium-Catalyzed Enantioselective Epoxidation

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Published in Tetrahedron Letters. 2002, vol. 43, no. 46, p. 8257-8260
Abstract TRISPHAT salts of chiral iminium cations allow, in combination with 18-C-6, the use of biphasic CH2Cl2/water conditions, which can improve the enantioselectivity of the oxone-mediated epoxidation. The combined use of lipophilic TRISPHAT counterions and 18-C-6 allows biphasic CH2Cl2/water conditions, which can improve the enantioselectivity of the oxone-mediated oxaziridinium-catalyzed epoxidation.
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LACOUR, Jérôme, MONCHAUD, David, MARSOL, Claire. Effect of the Medium on the Oxaziridinium-Catalyzed Enantioselective Epoxidation. In: Tetrahedron Letters, 2002, vol. 43, n° 46, p. 8257-8260. https://archive-ouverte.unige.ch/unige:7007

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Deposited on : 2010-06-18

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