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Scientific article
English

Diastereoselective rhodium-catalyzed nitrene transfer starting from chiral sulfonimidamide-derived iminoiodanes

Published inTetrahedron: asymmetry, vol. 16, no. 21, p. 3484-3487
Publication date2005
Abstract

The dirhodium-catalyzed aziridination of olefins with chiral sulfonimidamides as iminoiodane precursors has been investigated under stoichiometric conditions. Diastereoisomeric excesses of up to 82% have been achieved using [Rh2{(S)-nttl}4] as catalyst. Matching and mismatching effects were observed upon use of chiral rhodium(II) carboxylate catalysts.

Citation (ISO format)
FRUIT, Corinne et al. Diastereoselective rhodium-catalyzed nitrene transfer starting from chiral sulfonimidamide-derived iminoiodanes. In: Tetrahedron: asymmetry, 2005, vol. 16, n° 21, p. 3484–3487. doi: 10.1016/j.tetasy.2005.07.005
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