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Diastereoselective rhodium-catalyzed nitrene transfer starting from chiral sulfonimidamide-derived iminoiodanes

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Robert-Peillard, Fabien
Dodd, Robert H.
Dauban, Philippe
Published in Tetrahedron: Asymmetry. 2005, vol. 16, no. 21, p. 3484-3487
Abstract The dirhodium-catalyzed aziridination of olefins with chiral sulfonimidamides as iminoiodane precursors has been investigated under stoichiometric conditions. Diastereoisomeric excesses of up to 82% have been achieved using [Rh2{(S)-nttl}4] as catalyst. Matching and mismatching effects were observed upon use of chiral rhodium(II) carboxylate catalysts.
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FRUIT, Corinne et al. Diastereoselective rhodium-catalyzed nitrene transfer starting from chiral sulfonimidamide-derived iminoiodanes. In: Tetrahedron: Asymmetry, 2005, vol. 16, n° 21, p. 3484-3487. https://archive-ouverte.unige.ch/unige:6984

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Deposited on : 2010-06-18

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