Diastereoselective rhodium-catalyzed nitrene transfer starting from chiral sulfonimidamide-derived iminoiodanes

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Title		Diastereoselective rhodium-catalyzed nitrene transfer starting from chiral sulfonimidamide-derived iminoiodanes
Authors		Fruit, Corinne Robert-Peillard, Fabien Bernardinelli, Gérald Hugues Muller, Paul Dodd, Robert H. Dauban, Philippe
Published in		Tetrahedron: Asymmetry. 2005, vol. 16, no. 21, p. 3484-3487
Abstract		The dirhodium-catalyzed aziridination of olefins with chiral sulfonimidamides as iminoiodane precursors has been investigated under stoichiometric conditions. Diastereoisomeric excesses of up to 82% have been achieved using [Rh2{(S)-nttl}4] as catalyst. Matching and mismatching effects were observed upon use of chiral rhodium(II) carboxylate catalysts.
Identifiers		DOI: 10.1016/j.tetasy.2005.07.005
Full text		Article - Limited access to UNIGE
Structures		Faculté des sciences / Section de chimie et biochimie / Département de chimie organique
Citation (ISO format)		FRUIT, Corinne et al. Diastereoselective rhodium-catalyzed nitrene transfer starting from chiral sulfonimidamide-derived iminoiodanes. In: Tetrahedron: Asymmetry, 2005, vol. 16, n° 21, p. 3484-3487. doi: 10.1016/j.tetasy.2005.07.005 https://archive-ouverte.unige.ch/unige:6984