Diastereoselective rhodium-catalyzed nitrene transfer starting from chiral sulfonimidamide-derived iminoiodanes

Fruit, Corinne; Robert-Peillard, Fabien; Bernardinelli, Gérald Hugues; Muller, Paul; Dodd, Robert H.; Dauban, Philippe

doi:10.1016/j.tetasy.2005.07.005

Scientific article

English

Diastereoselective rhodium-catalyzed nitrene transfer starting from chiral sulfonimidamide-derived iminoiodanes

ContributorsFruit, Corinne; Robert-Peillard, Fabien; Bernardinelli, Gérald Hugues; Muller, Paul; Dodd, Robert H.; Dauban, Philippe

Published inTetrahedron: asymmetry, vol. 16, no. 21, p. 3484-3487

Publication date2005

Abstract

The dirhodium-catalyzed aziridination of olefins with chiral sulfonimidamides as iminoiodane precursors has been investigated under stoichiometric conditions. Diastereoisomeric excesses of up to 82% have been achieved using [Rh2{(S)-nttl}4] as catalyst. Matching and mismatching effects were observed upon use of chiral rhodium(II) carboxylate catalysts.

Affiliation

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

FRUIT, Corinne et al. Diastereoselective rhodium-catalyzed nitrene transfer starting from chiral sulfonimidamide-derived iminoiodanes. In: Tetrahedron: asymmetry, 2005, vol. 16, n° 21, p. 3484–3487. doi: 10.1016/j.tetasy.2005.07.005

Article

Identifiers

PID : unige:6984
DOI : 10.1016/j.tetasy.2005.07.005

ISSN of the journal0957-4166

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Diastereoselective rhodium-catalyzed nitrene transfer starting from chiral sulfonimidamide-derived iminoiodanes

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