TRISPHAT Anion. An Efficient NMR Chiral Shift Counterion for Cationic Tricarbonyl Manganese Complexes with Planar Chirality

Giner Planas, José; Prim, Damien; Rose, Eric; Rose-Munch, Françoise; Monchaud, David; Lacour, Jérôme

doi:10.1021/om010286w

Scientific article

English

TRISPHAT Anion. An Efficient NMR Chiral Shift Counterion for Cationic Tricarbonyl Manganese Complexes with Planar Chirality

ContributorsGiner Planas, José; Prim, Damien; Rose, Eric; Rose-Munch, Françoise; Monchaud, David; Lacour, Jérôme

Published inOrganometallics, vol. 20, no. 19, p. 4107-4110

Publication date2001

Abstract

The determination of the enantiomeric purity of chiral Mn(CO)3 complexes of substituted anisoles and toluenes is conveniently carried out by 1H NMR analysis after anion exchange with TRISPHAT, the chiral anion behaving as a diamagnetic chiral shift reagent.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

GINER PLANAS, José et al. TRISPHAT Anion. An Efficient NMR Chiral Shift Counterion for Cationic Tricarbonyl Manganese Complexes with Planar Chirality. In: Organometallics, 2001, vol. 20, n° 19, p. 4107–4110. doi: 10.1021/om010286w

Article

Identifiers

PID : unige:6939
DOI : 10.1021/om010286w

ISSN of the journal0276-7333

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TRISPHAT Anion. An Efficient NMR Chiral Shift Counterion for Cationic Tricarbonyl Manganese Complexes with Planar Chirality

The determination of the enantiomeric purity of chiral Mn(CO)3 complexes of substituted anisoles and toluenes is conveniently carried out by 1H NMR analysis after anion exchange with TRISPHAT, the chiral anion behaving as a diamagnetic chiral shift reagent.

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