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Scientific article
English

New trialkylsilyl enol ether chemistry: new regiospecific methodology for the synthesis of α,β-unsaturated cyclic ketones

Published inTetrahedron letters, vol. 33, no. 21, p. 2933-2936
Publication date1992
Abstract

Treatment of TIPS enol ethers with PhIO/TMSN3 followed by desilylation/elimination with fluoride ion gives good yields of the a,ß-unsaturated ketone. Treatment of triisopropylsilyl enol ethers with PhIO/TMSN3 followed by fluoride ion gives good yields of the a,ß-unsaturated ketone.

Affiliation Not a UNIGE publication
Citation (ISO format)
MAGNUS, Philip, EVANS, Andrew, LACOUR, Jérôme. New trialkylsilyl enol ether chemistry: new regiospecific methodology for the synthesis of α,β-unsaturated cyclic ketones. In: Tetrahedron letters, 1992, vol. 33, n° 21, p. 2933–2936. doi: 10.1016/S0040-4039(00)79564-5
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ISSN of the journal0040-4039
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