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Title

Total synthesis of the lycorenine-type Amaryllidaceae alkaloid (±)-clivonine via a biomimetic ring-switch from a lycorine-type progenitor

Authors
Mañas, Carles Giró
Paddock, Victoria L.
Spivey, Alan C.
White, Andrew J. P.
Mann, Inderjit
Oppolzer, Wolfgang
Published in Journal of the American Chemical Society. 2010, vol. 132, no. 14, p. 5176-5178
Abstract A fully diastereoselective total synthesis of the lycorenine-type Amaryllidaceae alkaloid (±)-clivonine (19) is reported via a route that employs for the first time a biomimetic ring-switch from a lycorine-type progenitor, thereby corroborating experimentally the biogenetic hypothesis first expounded for these compounds by Barton in 1960.
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MAÑAS, Carles Giró et al. Total synthesis of the lycorenine-type Amaryllidaceae alkaloid (±)-clivonine via a biomimetic ring-switch from a lycorine-type progenitor. In: Journal of the American Chemical Society, 2010, vol. 132, n° 14, p. 5176-5178. https://archive-ouverte.unige.ch/unige:6002

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Deposited on : 2010-04-19

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