Scientific article
OA Policy
English

Role of Disorder in the Thermodynamics and Atomic Dynamics of Glasses

Published inPhysical review letters, vol. 112, 025502
Publication date2014
Abstract

We measured the density of vibrational states (DOS) and the specific heat of various glassy and crystalline polymorphs of SiO2. The typical (ambient) glass shows a well-known excess of specific heat relative to the typical crystal (α-quartz). This, however, holds when comparing a lower-density glass to a higher-density crystal. For glassy and crystalline polymorphs with matched densities, the DOS of the glass appears as the smoothed counterpart of the DOS of the corresponding crystal; it reveals the same number of the excess states relative to the Debye model, the same number of all states in the low-energy region, and it provides the same specific heat. This shows that glasses have higher specific heat than crystals not due to disorder, but because the typical glass has lower density than the typical crystal.

Keywords
  • Thermodynamics
  • Atomic dynamics
  • Silica glass
  • Silica polymorph
  • Disorder
  • Boson peak
Affiliation entities Not a UNIGE publication
Citation (ISO format)
CHUMAKOV, A. I. et al. Role of Disorder in the Thermodynamics and Atomic Dynamics of Glasses. In: Physical review letters, 2014, vol. 112, p. 025502. doi: 10.1103/PhysRevLett.112.025502
Main files (1)
Article (Published version)
accessLevelPublic
Identifiers
Journal ISSN0031-9007
579views
452downloads

Technical informations

Creation17/03/2015 14:32:00
First validation17/03/2015 14:32:00
Update time14/03/2023 23:02:55
Status update14/03/2023 23:02:54
Last indexation30/10/2024 23:35:17
All rights reserved by Archive ouverte UNIGE and the University of GenevaunigeBlack