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Structural and spectroscopic studies on the alkali borohydrides MBH4 (M=Na,K,Rb,Cs)

Keller, L.
Published in Journal of Alloys and Compounds. 2004, vol. 375, no. 1-2, p. 98-106
Abstract Alkali borohydrides MBH[4] and their deuterides have been investigated by X-ray and neutron powder diffraction (M=K,Rb,Cs) and by infrared and Raman spectroscopy (M=Na,K,Rb,Cs). At room temperature the compounds crystallize with a cubic high temperature (HT) structure having FM[3]M symmetry in which the [BH4][−] complexes are disordered. At low temperature (LT) the potassium compound transforms into a tetragonal low temperature structure having P4[2]/n mc symmetry in which the [BH4][−] complexes are ordered such as in the isotypic sodium congener. The B---H distances within the complex as measured on the deuteride at 1.5 K are 1.205(3) Å. Indications for a partial ordering in the rubidium and cesium compounds exist but are not sufficient for a full structural characterization. Infrared and Raman spectra at room temperature are fully assigned for both hydrides and deuterides, including the overtones and combination bands, the Fermi resonance type interactions and the [10]B to [11]B splitting due to the presence of natural boron in the samples.
Keywords Hydrogen storage materialsCrystal structureX-ray and neutron diffractionInfrared and Raman spectroscopy
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Research group Groupe Hagemann
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RENAUDIN, Guillaume et al. Structural and spectroscopic studies on the alkali borohydrides MBH4 (M=Na,K,Rb,Cs). In: Journal of Alloys and Compounds, 2004, vol. 375, n° 1-2, p. 98-106. https://archive-ouverte.unige.ch/unige:3713

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Deposited on : 2009-10-06

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