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Title

Lifetimes of partial charge transfer exciplexes of 9-cyanophenanthrene and 9-cyanoanthracene

Authors
Dolotova, Elena
Dogadkin, Denis
Soboleva, Irina
Kuzmin, Michael
Published in Chemical Physics Letters. 2003, vol. 380, no. 5-6, p. 729-735
Abstract The fluorescence decays of several exciplexes with partial charge transfer have been investigated in solvents of various polarity. The measured lifetimes are found to be in reasonable agreement with the activation enthalpy and entropy of exciplex decay obtained earlier from the temperature dependence of the exciplex emission quantum yields. For exciplexes with 9-cyanophenanthrene substantial contribution of the higher local excited state into the exciplex electronic structure is found and borrowed intensity effect enhances the exciplex emission rate constants.
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Research group Groupe Vauthey
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DOLOTOVA, Elena et al. Lifetimes of partial charge transfer exciplexes of 9-cyanophenanthrene and 9-cyanoanthracene. In: Chemical Physics Letters, 2003, vol. 380, n° 5-6, p. 729-735. https://archive-ouverte.unige.ch/unige:3705

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Deposited on : 2009-10-06

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