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Title

External pressure and light influence on internal pressure in a spin-crossover solid [Zn : Fe(ptz)6](BF4)2

Authors
Ecolivet, C.
Published in High Pressure Research. 2003, vol. 23, no. 3, p. 359-363
Abstract The relation between the internal pressure during spin-crossover is compared to the chemical pressure induced by dilution with zinc. Further, the light of a specific LIESST (Light Induced Excited Spin State Trapping) wavelength is used to induce partial stabilisation of high-spin state and thus shift temperature of the spin-crossover towards lower values. The de-coupling of the spin-crossover and structural phase transition is discussed.
Keywords External and internal pressurePhotoexcitationSpin-crossoverFe(II) complex
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Structures
Research group Groupe Hauser
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JEFTIC, Jelena, ECOLIVET, C., HAUSER, Andreas. External pressure and light influence on internal pressure in a spin-crossover solid [Zn : Fe(ptz)6](BF4)2. In: High Pressure Research, 2003, vol. 23, n° 3, p. 359-363. https://archive-ouverte.unige.ch/unige:3689

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Deposited on : 2009-10-06

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