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unige:3533 
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Europium doped BaMgF4, an EPR and optical investigation |
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| Published in | Journal of Alloys and Compounds. 1998, vol. 268, no. 4, p. 60-65 | |
| Abstract | Eu2+ was introduced into pure and oxygen codoped BaMgF4 single crystals. A detailed EPR study of this ion (S=7/2) was realized on both types of systems. The result is that only one spectrum was observed involving a strong crystal field. The associated site symmetry of the impurity is Cs. It occupies very closely a Barium lattice site as was established by correlating the EPR results with those of a refined X-ray structure analysis on a Ba0.8Eu0.2MgF4 single crystal realized in our laboratory. The oxygen codoped crystals exhibited this same Eu2+ EPR spectrum (the only one). Optical emission and excitation experiments were performed between 13 000 and 53 000 cm−1. The results due to the Eu2+ impurity are given and discussed qualitatively within the 4f7left right double arrow4f65d1 scheme. | |
| Keywords | EPR — Luminescence — BaMgF4 — Hydrolysis | |
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| Research group | Groupe Bill | |
| Citation (ISO format) | REY, Julien M. et al. Europium doped BaMgF4, an EPR and optical investigation. In: Journal of Alloys and Compounds, 1998, vol. 268, n° 4, p. 60-65. https://archive-ouverte.unige.ch/unige:3533 |
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