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Luminescence and Energy Transfer of [Ru(bpy)3]2+, [Cr(ox)3]3-, and [Os(bpy)3]2+ in Three-Dimensional Oxalato-Networks

Published inThe journal of physical chemistry. A, vol. 104, no. 5, p. 883-893
Publication date2000
Abstract

Luminescence and energy transfer in [Zn1-xRux(bpy)3][NaAl1-yCry(ox)3] (x ≈ 0.01, y = 0.006 − 0.22; bpy = 2,2'-bipyridine, ox = C2O42-) and [Zn1-x-yRuxOsy(bpy)3][NaAl(ox)3] (x ≈ 0.01, y = 0.012) are presented and discussed. Surprisingly, the luminescence of the isolated luminophores [Ru(bpy)3]2+ and [Os(bpy)3]2+ in [Zn(bpy)3][NaAl(ox)3] is hardly quenched at room temperature. Steady-state luminescence spectra and decay curves show that energy transfer occurs between [Ru(bpy)3]2+ and [Cr(ox)3]3- and between [Ru(bpy)3]2+ and [Os(bpy)3]2+ in [Zn1-xRux(bpy)3][NaAl1-yCry(ox)3] and [Zn1-x-yRuxOsy(bpy)3] [NaAl(ox)3], respectively. For a quantitative investigation of the energy transfer, a shell type model is developed, using a Monte Carlo procedure and the structural parameters of the systems. A good description of the experimental data is obtained assuming electric dipole−electric dipole interaction between donors and acceptors, with a critical distance Rc for [Ru(bpy)3]2+ to [Cr(ox)3]3- energy transfer of 15 Å and for [Ru(bpy)3]2+ to [Os(bpy)3]2+ energy transfer of 33 Å. These values are in good agreement with those derived using the Förster−Dexter theory.

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HAZENKAMP-VON ARX, Marianne Elisabeth et al. Luminescence and Energy Transfer of [Ru(bpy)3]2+, [Cr(ox)3]3-, and [Os(bpy)3]2+ in Three-Dimensional Oxalato-Networks. In: The journal of physical chemistry. A, 2000, vol. 104, n° 5, p. 883–893. doi: 10.1021/jp993368v
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ISSN of the journal1089-5639
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