The identification and structure of FSO2 radical trapped in potassium sulphate crystals

Ravi Sekhar, Y.; Bill, Hans; Lovy, Dominique

doi:10.1016/0009-2614(87)87298-6

Article scientifique

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The identification and structure of FSO2 radical trapped in potassium sulphate crystals

Contributeurs/tricesRavi Sekhar, Y.; Bill, Hans; Lovy, Dominique

Publié dansChemical physics letters, vol. 136, no. 1, p. 57-61

Date de publication1987

Résumé

ESR and ENDOR results on irradiated K2SO4:BF4− crystals are presented. Based on the ESR spectra and their symmetry at the X and Ka bands, a new paramagnetic radical trapped at the sulphate sites is identified. The ENDOR spectra are consistent with the involvement of a fluorine nucleus. The spectra are assigned to the symmetric FSO2 radical.

Structure d'affiliation

Faculté des sciences / Section de chimie et biochimie / Département de chimie physique

Groupe de recherche

Groupe Bill

Citation (format ISO)

RAVI SEKHAR, Y., BILL, Hans, LOVY, Dominique. The identification and structure of FSO2 radical trapped in potassium sulphate crystals. In: Chemical physics letters, 1987, vol. 136, n° 1, p. 57–61. doi: 10.1016/0009-2614(87)87298-6

Identifiants

PID : unige:3091
DOI : 10.1016/0009-2614(87)87298-6

ISSN du journal0009-2614

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The identification and structure of FSO2 radical trapped in potassium sulphate crystals

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