Other version: http://www3.interscience.wiley.com/cgi-bin/fulltext?ID=66004317&PLACEBO=IE.pdf
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Gold(I) and Gold(0) complexes of phosphinine-based macrocycles |
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Published in | Angewandte Chemie. International edition in English. 1999, vol. 38, no. 21, p. 3194-3197 | |
Abstract | A CO-like matrix, showing coordination analogous to that of carbonyl groups, is provided by silacalix[4]phosphinine macrocycles. Reaction with AuI leads to the first gold(I) complexes of macrocycles, which can be reduced with sodium or potassium to the paramagnetic gold(0) complexes (an example is shown), as evidenced by cyclic voltammetry and EPR spectroscopy. | |
Keywords | Gold — Heterocycles — Macrocyclic ligands — Phosphinines — P ligands | |
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Research group | Groupe Geoffroy | |
Citation (ISO format) | MÉZAILLES, Nicolas et al. Gold(I) and Gold(0) complexes of phosphinine-based macrocycles. In: Angewandte Chemie. International edition in English, 1999, vol. 38, n° 21, p. 3194-3197. doi: 10.1002/(SICI)1521-3773(19991102)38:21<3194::AID-ANIE3194>3.0.CO;2-O https://archive-ouverte.unige.ch/unige:2746 |