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Scientific article
English

Gold(I) and Gold(0) complexes of phosphinine-based macrocycles

Published inAngewandte Chemie. International edition in English, vol. 38, no. 21, p. 3194-3197
Publication date1999
Abstract

A CO-like matrix, showing coordination analogous to that of carbonyl groups, is provided by silacalix[4]phosphinine macrocycles. Reaction with AuI leads to the first gold(I) complexes of macrocycles, which can be reduced with sodium or potassium to the paramagnetic gold(0) complexes (an example is shown), as evidenced by cyclic voltammetry and EPR spectroscopy.

Keywords
  • Gold
  • Heterocycles
  • Macrocyclic ligands
  • Phosphinines
  • P ligands
Research group
Citation (ISO format)
MÉZAILLES, Nicolas et al. Gold(I) and Gold(0) complexes of phosphinine-based macrocycles. In: Angewandte Chemie. International edition in English, 1999, vol. 38, n° 21, p. 3194–3197. doi: 10.1002/(SICI)1521-3773(19991102)38:21<3194::AID-ANIE3194>3.0.CO;2-O
ISSN of the journal0570-0833
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