Gold(I) and Gold(0) complexes of phosphinine-based macrocycles

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Title		Gold(I) and Gold(0) complexes of phosphinine-based macrocycles
Authors		Mézailles, Nicolas Avarvari, Narcis Maigrot, Nicole Ricard, Louis Mathey, François Le Floch, Pascal Cataldo, Laurent Berclaz, Théo Geoffroy, Michel show all authors [1 - 9]
Published in		Angewandte Chemie. International edition in English. 1999, vol. 38, no. 21, p. 3194-3197
Abstract		A CO-like matrix, showing coordination analogous to that of carbonyl groups, is provided by silacalix[4]phosphinine macrocycles. Reaction with AuI leads to the first gold(I) complexes of macrocycles, which can be reduced with sodium or potassium to the paramagnetic gold(0) complexes (an example is shown), as evidenced by cyclic voltammetry and EPR spectroscopy.
Keywords		Gold — Heterocycles — Macrocyclic ligands — Phosphinines — P ligands
Identifiers		DOI: 10.1002/(SICI)1521-3773(19991102)38:21<3194::AID-ANIE3194>3.0.CO;2-O
Full text		Other version: http://www3.interscience.wiley.com/cgi-bin/fulltext?ID=66004317&PLACEBO=IE.pdf
Structures		Faculté des sciences / Section de chimie et biochimie / Département de chimie physique
Research group		Groupe Geoffroy
Citation (ISO format)		MÉZAILLES, Nicolas et al. Gold(I) and Gold(0) complexes of phosphinine-based macrocycles. In: Angewandte Chemie. International edition in English, 1999, vol. 38, n° 21, p. 3194-3197. doi: 10.1002/(SICI)1521-3773(19991102)38:21<3194::AID-ANIE3194>3.0.CO;2-O https://archive-ouverte.unige.ch/unige:2746

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