[4+2] Cycloadducts between enantiopure tetramethyl-BEDT-TTF and ortho-chloranil: conformational issues in the solid state

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Title		[4+2] Cycloadducts between enantiopure tetramethyl-BEDT-TTF and ortho-chloranil: conformational issues in the solid state
Authors		Pop, Flavia Lacour, Jérôme Avarvari, Narcis
Published in		Revue roumaine de chimie. 2012, vol. 57, no. 4-5, p. 457-462
Abstract		The unexpected formation, in electrocrystallization experiments, and structural characterization of enantiopure [4+2] cycloadducts between the enantiopure donors tetramethyl-bis(ethylenedithio)-tetrathiafulvalene (TMBEDT-TTF) as (R,R,R,R) and (S,S,S,S) enantiomers and ortho-chloranil are described. Single crystal X-ray analysis reveals the presence of axial and equatorial methyl groups within the same molecule in the solid state, and the establishment of intermolecular hydrogen bonds of Cl···H3Ceq type.
Full text		Article (Published version) (472 Kb) - Limited access to UNIGE
Structures		Faculté des sciences / Section de chimie et biochimie / Département de chimie organique
Citation (ISO format)		POP, Flavia, LACOUR, Jérôme, AVARVARI, Narcis. [4+2] Cycloadducts between enantiopure tetramethyl-BEDT-TTF and ortho-chloranil: conformational issues in the solid state. In: Revue roumaine de chimie, 2012, vol. 57, n° 4-5, p. 457-462. https://archive-ouverte.unige.ch/unige:26399

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Deposited on : 2013-02-19

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