[4+2] Cycloadducts between enantiopure tetramethyl-BEDT-TTF and ortho-chloranil: conformational issues in the solid state

Pop, Flavia; Lacour, Jérôme; Avarvari, Narcis

Scientific article

English

[4+2] Cycloadducts between enantiopure tetramethyl-BEDT-TTF and ortho-chloranil: conformational issues in the solid state

ContributorsPop, Flavia; Lacour, Jérôme

; Avarvari, Narcis

Published inRevue roumaine de chimie, vol. 57, no. 4-5, p. 457-462

Publication date2012

Abstract

The unexpected formation, in electrocrystallization experiments, and structural characterization of enantiopure [4+2] cycloadducts between the enantiopure donors tetramethyl-bis(ethylenedithio)-tetrathiafulvalene (TMBEDT-TTF) as (R,R,R,R) and (S,S,S,S) enantiomers and ortho-chloranil are described. Single crystal X-ray analysis reveals the presence of axial and equatorial methyl groups within the same molecule in the solid state, and the establishment of intermolecular hydrogen bonds of Cl···H3Ceq type.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

POP, Flavia, LACOUR, Jérôme, AVARVARI, Narcis. [4+2] Cycloadducts between enantiopure tetramethyl-BEDT-TTF and ortho-chloranil: conformational issues in the solid state. In: Revue roumaine de chimie, 2012, vol. 57, n° 4-5, p. 457–462.

Article (Published version)

Identifiers

PID : unige:26399

ISSN of the journal0035-3930

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[4+2] Cycloadducts between enantiopure tetramethyl-BEDT-TTF and ortho-chloranil: conformational issues in the solid state

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