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Scientific article
English

Evaluation of the Chiral DIANANE Backbone as Ligand for Organolithium Reagents

Published inAdvanced synthesis & catalysis, vol. 354, no. 9, p. 1780-1790
Publication date2012
Abstract

Novel endo,endo-2,5-diaminonorbonane-derived tertiary C2-symmetrical diamines were synthesized via the one-pot reductive amination of enantiomerically pure norbornane-2,5-dione. These ligands were applied to various catalytic reactions such as asymmetric deprotonation, asymmetric bromine-lithium exchange, and enantioselective addition of aryl- and allkylithium reagents to aromatic aldimines.

Keywords
  • Asymmetric catalysis
  • Bromine-lithium exchange
  • Deprotonation
  • Endo,endo-2,5-diaminonorbonane derivatives
  • Nucleophilic addition
  • Organolithium compounds
Citation (ISO format)
PRAZ, Jezabel et al. Evaluation of the Chiral DIANANE Backbone as Ligand for Organolithium Reagents. In: Advanced synthesis & catalysis, 2012, vol. 354, n° 9, p. 1780–1790. doi: 10.1002/adsc.201101016
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ISSN of the journal1615-4150
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Creation06/26/2012 2:49:00 PM
First validation06/26/2012 2:49:00 PM
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