Scientific article
OA Policy
English

Role of the coupling of the electronic transitions on the order of the metal-to-insulator phase transition in nickelates

Published inAPL materials, vol. 12, no. 8, 081120
Publication date2024-08-19
Abstract

Rare-earth nickelates (chemical formula RNiO3, R being a rare-earth cation) display a temperature-dependent metal-to-insulator transition (MIT) together with a breathing distortion of the NiO6 octahedra units at a temperature ranging from 0 to 600 K depending on the size of the R cation. Their rich phase diagram is also characterized by a paramagnetic to antiferromagnetic transition that occurs at the same temperature as the MIT for R = Pr, Nd, while it arises at lower temperatures for all the other members of the series. In this work, we have investigated the order of the MIT in a portion of the phase diagram spanning from SmNiO3 to NdNiO3 by means of temperature dependent transport measurements and resonant elastic x-ray scattering performed on high quality epitaxial SmxNd1−xNiO3 solid solution thin films. Our results show that the order of the metal-to-insulator transition does not depend on whether or not the MIT is coupled with the magnetic transition.

Keywords
  • Phase transitions
  • Energy dispersive x-ray spectroscopy
  • Thin films
  • Transmisison elelctron microscopy
  • Nickelates
  • Antiferromagnetism
Research groups
Citation (ISO format)
VARBARO, Lucia et al. Role of the coupling of the electronic transitions on the order of the metal-to-insulator phase transition in nickelates. In: APL materials, 2024, vol. 12, n° 8, p. 081120. doi: 10.1063/5.0221334
Main files (1)
Article (Published version)
Identifiers
Journal ISSN2166-532X
66views
16downloads

Technical informations

Creation24/10/2024 07:50:31
First validation28/10/2024 11:05:32
Update time30/10/2024 13:33:50
Status update30/10/2024 13:33:50
Last indexation24/04/2025 08:23:44
All rights reserved by Archive ouverte UNIGE and the University of GenevaunigeBlack