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Novel multimethod approach for the determination of the colloidal stability of nanomaterials in complex environmental mixtures using a global stability index: TiO2 as case study

Publié dansScience of the Total Environment, vol. 801, no. 149607
Date de publication2021
Résumé

A systematic study on the colloidal behavior of uncoated and polyvinylpyrrolidone (PVP) coated TiO2 engineered nanomaterials (ENMs) in simulated aqueous media is herein reported, in which conditions representative for natural waters (pH, presence of divalent electrolytes (i.e. Ca2+/Mg2+ and SO4 2−), of natural organic matter (NOM) and of suspended particulate matter (SPM)) were systematically varied. The colloidal stability of the different dispersions was investigated by means of Dynamic and Electrophoretic Light Scattering (DLS and ELS) and Centrifugal Separation Analysis (CSA), and a global stability index based on these three techniques was developed. The index allows to quantitatively classify the nano-based dispersions according to their colloidal stability affected by the different parameters studied. This multimethod approach clearly identifies inorganic SPM followed by divalent electrolytes as the main natural components destabilizing TiO2 ENMs upon entering in simulated natural waters, while it highlights a moderate stabilization induced by NOM, depending mainly on pH. Moreover, the PVP coating was found to attenuate the influence of these parameters on the colloidal stability. The obtained results show how the global stability index developed is influenced by the complexity of the system, suggesting the importance of combining the information gathered from all the techniques employed to better elucidate the fate and behavior of ENMs in natural surface waters.

Mots-clés
  • TiO2 nanomaterials
  • Natural organic matter
  • Suspended particulate matter
  • Multidimensional parameter matrix
  • Multimethod approach
  • Global stability index
Financement
  • European Commission - Nanomaterial FAte and Speciation in the Environment [646002]
Citation (format ISO)
BADETTI, Elena et al. Novel multimethod approach for the determination of the colloidal stability of nanomaterials in complex environmental mixtures using a global stability index: TiO<sub>2</sub> as case study. In: Science of the Total Environment, 2021, vol. 801, n° 149607. doi: 10.1016/j.scitotenv.2021.149607
Fichiers principaux (1)
Article (Published version)
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Identifiants
ISSN du journal0048-9697
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Informations techniques

Création30/08/2021 13:18:00
Première validation30/08/2021 13:18:00
Heure de mise à jour16/03/2023 01:10:46
Changement de statut16/03/2023 01:10:45
Dernière indexation06/05/2024 08:00:56
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