Département de chimie organique

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2018

Scientific Articles

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A cell-penetrating artificial metalloenzyme regulates a gene switch in a designer mammalian cellOkamoto, Yasunori; Kojima, Ryosuke; Schwizer, Fabian; Bartolami, Eline; ... Ward, Thomas R.
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A General Nickel-Catalyzed Kumada Vinylation for the Preparation of 2-Substituted 1,3-DienesFiorito, Daniele; Folliet, Sarah; Liu, Yangbin; Mazet, Clement;
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Accelerating Turnover Frequency in Nucleic Acid Templated ReactionsChang, Dalu; Kim, Kitae; Lindberg, Eric; Winssinger, Nicolas;
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Anion-π Catalysis: Focus on Nonadjacent StereocentersZhang, Xiang; Liu, Le; Lopez Andarias, Javier; Wang, Chao; ... Matile, Stefan
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Biography of Professor Nicolaou: a journey to the extremes of molecular complexityWinssinger, Nicolas;
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Catalysis with Pnictogen, Chalcogen, and Halogen BondsBenz, Sebastian; Poblador Bahamonde, Amalia Isabel; Low-Der's, Nicolas Vinh Tri; Matile, Stefan;
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Chimeric Streptavidins as Host Proteins for Artificial MetalloenzymesPellizzoni, Michela M.; Schwizer, Fabian; Wood, Christopher W.; Sabatino, Valerio; ... Ward, Thomas R.
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Cysteine-reactive probes and their use in chemical proteomicsHoch, Dominic Gregor; Abegg, Daniel; Adibekian, Alexander;
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Detecting order and lateral pressure at biomimetic interfaces using a mechanosensitive second-harmonic-generation probeLicari, Giuseppe Léonardo; Beckwith, Joseph; Soleimanpour, Saeideh; Matile, Stefan; Vauthey, Eric
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Diselenolane-mediated cellular uptakeChuard, Nicolas; Poblador Bahamonde, Amalia Isabel; Zong, Lili; Bartolami, Eline; ... Matile, Stefan
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Double-Stranded RNA-Specific Templated Reaction with Triplex Forming PNAKim, Kitae; Chang, Dalu; Winssinger, Nicolas;
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Efficient Synthesis of Ditopic Polyamide Receptors for Cooperative Ion Pair Recognition in Solution and Solid StatesRay, Sumit Kumar; Homberg, Alexandre; Vishe, Mahesh; Besnard, Céline; Lacour, Jérôme
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Excimer-Based On-Off Bis(pyreneamide) Macrocyclic ChemosensorsVishe, Mahesh; Lathion, Timothee; Pascal, Simon; Yushchenko, Oleksandr; ... Lacour, Jérôme
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Exploring the mechanism of the Pd-catalyzed spirocyclization reaction: a combined DFT and experimental studyFranzoni, Ivan; Yoon, Hyung; García-López, José-Antonio; Poblador Bahamonde, Amalia Isabel; Lautens, Mark
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Ganglioside-Selective Mechanosensitive Fluorescent Membrane ProbesStrakova, Karolina; Soleimanpour, Saeideh; Diez Castellnou, Marta; Sakai, Naomi; Matile, Stefan
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Glycosylated Cell-Penetrating Poly(disulfide)s: Multifunctional Cellular Uptake at High SolubilityMorelli, Paola; Bartolami, Eline; Sakai, Naomi; Matile, Stefan;
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Imine-based [2]catenanes in waterCaprice, Kenji; Pupier, Marion; Kruve, Anneli; Schalley, Christoph A.; Cougnon, Fabien
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Ion Transfer Voltammetry at Thin Films Based on Functionalized Cationic [6]HelicenesJarolimova, Zdenka; Bosson, Johann; Labrador Beltran, Maria Géraldine; Lacour, Jérôme; Bakker, Eric
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Mechanosensitive Oligodithienothiophenes: Transmembrane Anion Transport Along Chalcogen-Bonding CascadesMacchione, Mariano; Tsemperouli, Maria; Goujon, Antoine; Mallia, Ajith; ... Matile, Stefan
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Mitochondria-specific photoactivation to monitor local sphingosine metabolism and functionFeng, Suihan; Harayama, Takeshi; Montessuit, Sylvie; David, Fabrice Pierre André; ... Riezman, Howard
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Multicatalytic Stereoselective Synthesis of Highly Substituted Alkenes by Sequential Isomerization/Cross-Coupling ReactionsRomano, Ciro; Mazet, Clement;
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Peptide nucleic acid-templated selenocystine–selenoester ligation enables rapid miRNA detectionSayers, Jessica; Payne, Richard J.; Winssinger, Nicolas;
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Polycyclic Indoline-Benzodiazepines through Electrophilic Additions of α-Imino Carbenes to Tröger BasesBosmani, Alessandro; Guarnieri Ibanez, Alejandro José; Goudedranche, Sébastien; Besnard, Céline; Lacour, Jérôme
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Ruthenium-based Photocatalysis in Templated ReactionsSaarbach, Jacques; Lindberg, Eric; Winssinger, Nicolas;
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Software tools and tutorials in liquid state NMRJeannerat, Damien;
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Synergistic Anion–(π)n–π Catalysis on π-Stacked FoldamersBornhof, Anna-Bea; Bauza, Antonio; Aster, Alexander; Pupier, Marion; ... Matile, Stefan
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Synthesis of deoxyelephantopin analoguesLagoutte, Roman; Serba, Christelle; Winssinger, Nicolas;

Doctoral Thesis

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Cell-penetrating poly(disulfide)s: focus on sidechain engineeringMorelli, Paola;

2017

Scientific Articles

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10th Young Faculty Meeting, 6th June 2017Cougnon, Fabien; Ruggi, Albert; Merz, Leo;
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Anion-π Catalysis of Diels-Alder ReactionsLiu, Le; Cotelle, Yoann; Bornhof, Anna-Bea; Besnard, Céline; ... Matile, Stefan
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Anion-π Catalysts with Axial ChiralityWang, Chao; Matile, Stefan;
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Anion-π transaminase mimicsLiu, Le; Matile, Stefan;
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Anion–π catalysis: bicyclic products with four contiguous stereogenic centers from otherwise elusive diastereospecific domino reactions on π-acidic surfacesLiu, Le; Cotelle, Yoann; Klehr, Juliane; Sakai, Naomi; ... Matile, Stefan
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Anion−π Catalysis on FullerenesLopez Andarias, Javier; Frontera, Antonio; Matile, Stefan;
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Bright Electrochemiluminescence Tunable in the Near-Infrared of Chiral Cationic Helicene ChromophoresLi, Haidong; Wallabregue, Antoine; Adam, Catherine; Labrador Beltran, Maria Géraldine; ... Sojic, Neso
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Catalysis with Chalcogen BondsBenz, Sebastian; Lopez Andarias, Javier; Mareda, Jiri; Sakai, Naomi; Matile, Stefan
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Catalysis with chalcogen bonds: neutral benzodiselenazole scaffolds with high-precision selenium donors of variable strengthBenz, Sebastian; Mareda, Jiri; Besnard, Céline; Sakai, Naomi; Matile, Stefan
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Computational Study of the Cu-Free Allylic Alkylation Mechanism with Grignard Reagents: Role of the NHC LigandPoblador Bahamonde, Amalia Isabel; Halbert, Stéphanie;
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Correlation of surface pressure and hue of planarizable push–pull chromophores at the air/water interfaceNeuhaus, Frederik; Zobi, Fabio; Brezesinski, Gerald; Dal Molin, Marta; ... Zumbuehl, Andréas
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Covalent inhibitors : an opportunity for rational target selectivityLagoutte, Roman; Patouret, Rémi; Winssinger, Nicolas;
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Critical Analysis of Rate Constants and Turnover Frequency in Nucleic Acid-Templated Reactions: Reaching Terminal VelocityChang, Dalu; Lindberg, Eric; Winssinger, Nicolas;
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Diversity-oriented synthesis of heterocycles and macrocycles by controlled reactions of oxetanes with α-iminocarbenesGuarnieri Ibanez, Alejandro José; Medina, Florian; Besnard, Céline; Kidd, Sarah L.; ... Lacour, Jérôme
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Dynamic cooperative glycan assembly blocks the binding of bacterial lectins to epithelial cellsMachida, Takuya; Novoa, Alexandre; Gillon, Émilie; Zheng, Shuangshuang; ... Winssinger, Nicolas
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Efficient annihilation electrochemiluminescence of cationic helicene luminophoresLi, Haidong; Voci, Silvia; Wallabregue, Antoine; Adam, Catherine; ... Sojic, Neso
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Efficient Delivery of Quantum Dots into the Cytosol of Cells Using Cell-Penetrating Poly(disulfide)sDerivery, Emmanuel; Bartolami, Eline; Matile, Stefan; Gonzalez Gaitan, Marcos;
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Electric-Field-Assisted Anion−π CatalysisAkamatsu, Masaaki; Sakai, Naomi; Matile, Stefan;
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Elimination of signals tilting caused by B0 field inhomogeneity using 2D-lineshape reference deconvolutionSheberstov, Kirill; Sinitsyn, Dmitry O.; Cheshkov, Dmitry A.; Jeannerat, Damien;
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Enantiospecific Elongation of Cationic Helicenes by Electrophilic Functionalization at Terminal EndsDuwald, Romain; Pascal, Simon; Bosson, Johann; Grass, Stéphane; ... Lacour, Jérôme
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Epidithiodiketopiperazines : strain-promoted thiol-mediated cellular uptake at the highest tensionZong, Lili; Bartolami, Eline; Abegg, Daniel; Adibekian, Alexander; ... Matile, Stefan
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Exploring site selectivity of Iridium hydride insertion into allylic alcohols: serendipitous discovery and comparative study of organic and organometallic catalysts for the vinylogous peterson eliminationLi, Houhua; Fiorito, Daniele; Mazet, Clement;
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Facile access to modified and functionalized PNAs through Ugi-based solid phase oligomerizationSaarbach, Jacques; Masi, Daniela; Zambaldo, Claudio; Winssinger, Nicolas;
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Following the Lead from Nature with Covalent InhibitorsLagoutte, Roman; Winssinger, Nicolas;
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Human- and computer-accessible 2D correlation data for a more reliable structure determination of organic compoundsJeannerat, Damien;
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Influence of the dissolution solvent on the cytotoxicity of octahedral cationic Ir(III) hydride complexesHuang, Huaiyi; Humbert, Nicolas; Bizet, Vincent; Patra, Malay; ... Gasser, Gilles
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Kinase-templated abiotic reactionSaarbach, Jacques; Lindberg, Eric; Folliet, Sarah; Georgeon, S.; ... Winssinger, Nicolas
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Mechanistic Investigation of the Pd-Catalyzed Intermolecular Carboetherification and Carboamination of 2,3-Dihydrofuran: Similarities, Differences, and Evidence for Unusual Reaction IntermediatesBorrajo Calleja, Gustavo; Bizet, Vincent; Besnard, Céline; Mazet, Clement;
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Palladium-Catalyzed Hydrohalogenation of 1,6-Enynes: Hydrogen Halide Salts and Alkyl Halides as Convenient HX SurrogatesPetrone, David A.; Franzoni, Ivan; Ye, Juntao; Rodríguez, José F.; ... Lautens, Mark
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Planarizable push-pull probes : overtwisted flipper mechanophoresMacchione, Mariano; Chuard, Nicolas; Sakai, Naomi; Matile, Stefan;
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Regioselective and Enantiospecific Synthesis of Dioxepines by (Cyclopentadienyl)ruthenium-Catalyzed Condensations of Diazocarbonyls and OxetanesEgger, Leo; Guenee, Laure; Buergi, Thomas; Lacour, Jérôme;
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Rhodium-Catalyzed Enantioselective Isomerization of meso-Oxabenzonorbornadienes to 1,2-Naphthalene OxidesYen, Andy; Choo, Ken-Loon; Yazdi, Shabnam K.; Franke, Patrick T.; ... Lautens, Mark
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Sidechain Engineering in Cell-Penetrating Poly(disulfide)sMorelli, Paola; Matile, Stefan;
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Stereoselective and Enantiospecific Mono- and Bis-C−H Azidation of Tröger Bases : Insight on Bridgehead Iminium Intermediates and Application to Anion-Binding CatalysisBosmani, Alessandro; Pujari, Sandip; Besnard, Céline; Guenee, Laure; ... Lacour, Jérôme
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Strain-Promoted Thiol-Mediated Cellular Uptake of Giant Substrates: Liposomes and PolymersomesChuard, Nicolas; Gasparini, Giulio; Moreau, Dimitri; Lörcher, Samuel; ... Matile, Stefan
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Strained Cyclic Disulfides Enable Cellular Uptake by Reacting with the Transferrin ReceptorAbegg, Daniel; Gasparini, Giulio; Hoch, Dominic Gregor; Shuster, Anton; ... Adibekian, Alexander
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Targeted Isolation of Monoterpene Indole Alkaloids from Palicourea sessilisKlein-Júnior, Luiz C.; Cretton, Sylvian; Allard, Pierre-Marie; Genta-Jouve, Grégory; ... Henriques, Amélia T.
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The SAGA complex, together with transcription factors and the endocytic protein Rvs167p, coordinates the reprofiling of gene expression in response to changes in sterol composition in Saccharomyces cerevisiaeDewhurst, Gisele; Abegg, Daniel; David, Fabrice P. A.; Rougemont, Jacques; ... Riezman, Howard
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Tight Embrace in a Molecular Knot with Eight CrossingsCougnon, Fabien;
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[4]Helicene-Squalene Fluorescent Nanoassemblies for Specific Targeting of Mitochondria in Live-Cell ImagingBabic, Andréj; Pascal, Simon; Duwald, Romain; Moreau, Dimitri; ... Allémann, Eric

Book Chapters

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Analysis of the Phases of Signals in Two-Dimensional NMRJeannerat, Damien;

Doctoral Thesis

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Development of chemical protein glycosylation, multivalent carbohydrates, and folded peptide-PNA catalystMachida, Takuya;
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Mechanosensitive membrane probes: emphasis on stable, modifiable and target-specific headgroupsSoleimanpour, Saeideh;
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Novel chemical proteomics methods to discover targets of cysteine reactive moleculesAbegg, Daniel;
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Pd-catalyzed regio-, diastereo- and enantioselective cross-coupling reactions of dihydrofuransBorrajo Calleja, Gustavo;
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Rylenediimide model systems: quantification of enolate-π interactions for anion-π catalysisMiros, François;
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Synthesis and properties of functionalization cationic [4]helicenes and triangulenesHernandez Delgado, Irene;
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Synthesis, late-stage functionalization and properties of cationic [6]helicenes chromophoresLabrador Beltran, Maria Géraldine;

2016

Scientific Articles

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A novel HSP90 inhibitor with reduced hepatotoxicity synergizes with radiotherapy to induce apoptosis, abrogate clonogenic survival, and improve tumor control in models of colorectal cancerKinzel, Linda; Ernst, Anne; Orth, Michael; Albrecht, Valerie; ... Lauber, Kirsten
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A ratiometric luminescent switch based on platinum complexes tethered to a crown-ether scaffoldSinn, Stephan; Biedermann, Frank; Vishe, Mahesh; Aliprandi, Alessandro; ... De Cola, Luisa
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Activation of Cell-Penetrating Peptides with Ionpair−π Interactions and FluorophilesChuard, Nicolas; Fujisawa, Kaori; Morelli, Paola; Saarbach, Jacques; ... Matile, Stefan
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Allosterically Regulated Phosphatase Activity from Peptide-PNA Conjugates Folded Through HybridizationMachida, Takuya; Dutt, Som; Winssinger, Nicolas;
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Anion Transport with Chalcogen BondsBenz, Sebastian; Macchione, Mariano; Verolet, Quentin; Mareda, Jiri; ... Matile, Stefan
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Anion-π Catalysis of Enolate Chemistry: Rigidified Leonard Turns as a General Motif to Run Reactions on Aromatic SurfacesCotelle, Yoann; Benz, Sebastian; Avestro, Alyssa-Jennifer; Ward, Thomas R.; ... Matile, Stefan
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Anion-π EnzymesCotelle, Yoann; Lebrun, Vincent; Sakai, Naomi; Ward, Thomas R.; Matile, Stefan
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Asymmetric Anion-π Catalysis on PerylenediimidesWang, Chao; Miros, François; Mareda, Jiri; Sakai, Naomi; Matile, Stefan
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Asymmetric Anion−π Catalysis of Iminium/Nitroaldol Cascades To Form Cyclohexane Rings with Five Stereogenic Centers Directly on π-Acidic SurfacesLiu, Le; Cotelle, Yoann; Avestro, Alyssa-Jennifer; Sakai, Naomi; Matile, Stefan
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Catalytic Enantioselective Total Synthesis of Riccardiphenol BCottet, Pierre; Bleschke, Christian Alexander; Guiteras Capdevila, Montserrat; Tissot, Matthieu; Alexakis, Alexandre
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Characterization of Dimethylsulfoxide / Glycerol Mixtures: A Binary Solvent System for the Study of "Friction-Dependent" Chemical ReactivityAngulo Nunez, Gonzalo Manuel; Brucka, Anna; Gerecke, Mario; Grampp, Günter; ... Wnuk, Paweł
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Chemoproteomics-Enabled Discovery of a Potent and Selective Inhibitor of the DNA Repair Protein MGMTWang, Chao; Abegg, Daniel; Hoch, Dominic Gregor; Adibekian, Alexander;
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Computational Study on the Mechanism of the Palladium-Catalyzed Arylation of α,β-Unsaturated AldehydesFranzoni, Ivan; Poblador Bahamonde, Amalia Isabel;
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Configurationally Stable Doubly Bridged Biphenyl Azocines through Copper-Catalyzed Double Carbene Insertions into the Corresponding AzepinesHarthong, Steven; Brun, Elodie; Grass, Stéphane; Besnard, Céline; ... Lacour, Jérôme
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Copper-Catalyzed Enantioselective Conjugate Addition to α,β-Unsaturated Aldehydes with Various Organometallic ReagentsContal, Sylvie; Gremaud, Ludovic; Palais, Laetitia; Babel, Lucille; Alexakis, Alexandre
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Core-Substituted Naphthalenediimides: LUMO Levels Revisited, in Comparison with Preylenediimides with Sulfur Redox Switches in the CoreMiros, François; Matile, Stefan;
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Cutting Edge Chemical Biology: Report from the 2016 International Symposium on Chemical Biology, January 13–15, Geneva, SwitzerlandAdibekian, Alexander; Stallforth, Pierre;
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Cysteine-specific Chemical Proteomics: From Target Identification to Drug DiscoveryHoch, Dominic Gregor; Abegg, Daniel; Wang, Chao; Shuster, Anton; Adibekian, Alexander
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Dipolar Photosystems: Engineering Oriented Push-Pull Components into Double- and Triple-Channel Surface ArchitecturesBolag, Alatengbaolige; Sakai, Naomi; Matile, Stefan;
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Direct Access to Furoindolines by Palladium-Catalyzed Intermolecular CarboaminationBizet, Vincent; Borrajo Calleja, Gustavo; Besnard, Céline; Mazet, Clement;
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Direct Organocatalysed Double Michael Addition of α-Angelica Lactone to EnonesLagoutte, Roman; Besnard, Céline; Alexakis, Alexandre;
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Discrimination of hexabromocyclododecane from new polymeric brominated flame retardant in polystyrene foam by nuclear magnetic resonanceJeannerat, Damien; Pupier, Marion; Schweizer, Sébastien; Mitrev, Yavor Nikolaev; ... Kohler, Marcel
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Divergent synthesis and identification of the cellular targets of deoxyelephantopinsLagoutte, Roman; Serba, Christelle; Abegg, Daniel; Hoch, Dominic Gregor; ... Winssinger, Nicolas
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Duplex formation and secondary structure of γ-PNA observed by NMR and CDViéville, J.M.P.; Barluenga Badiola, Sofia; Winssinger, Nicolas; Delsuc, M.A.;
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