Département de chimie organique

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2017

Scientific Articles

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Anion-π Catalysts with Axial ChiralityWang, Chao; Matile, Stefan;
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Anion-π transaminase mimicsLiu, Le; Matile, Stefan;
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Anion–π catalysis: bicyclic products with four contiguous stereogenic centers from otherwise elusive diastereospecific domino reactions on π-acidic surfacesLiu, Le; Cotelle, Yoann; Klehr, Juliane; Sakai, Naomi; ... Matile, Stefan
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Bright Electrochemiluminescence Tunable in the Near-Infrared of Chiral Cationic Helicene ChromophoresLi, Haidong; Wallabregue, Antoine; Adam, Catherine; Labrador Beltran, Maria Géraldine; ... Sojic, Neso
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Catalysis with Chalcogen BondsBenz, Sebastian; Lopez Andarias, Javier; Mareda, Jiri; Sakai, Naomi; Matile, Stefan
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Correlation of surface pressure and hue of planarizable push–pull chromophores at the air/water interfaceNeuhaus, Frederik; Zobi, Fabio; Brezesinski, Gerald; Dal Molin, Marta; ... Zumbuehl, Andréas
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Covalent inhibitors : an opportunity for rational target selectivityLagoutte, Roman; Patouret, Rémi; Winssinger, Nicolas;
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Critical Analysis of Rate Constants and Turnover Frequency in Nucleic Acid-Templated Reactions: Reaching Terminal VelocityChang, Dalu; Lindberg, Eric; Winssinger, Nicolas;
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Diversity-oriented synthesis of heterocycles and macrocycles by controlled reactions of oxetanes with α-iminocarbenesGuarnieri Ibanez, Alejandro José; Medina, Florian; Besnard, Céline; Kidd, Sarah L.; ... Lacour, Jérôme
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Dynamic cooperative glycan assembly blocks the binding of bacterial lectins to epithelial cellsMachida, Takuya; Novoa, Alexandre; Gillon, Émilie; Zheng, Shuangshuang; ... Winssinger, Nicolas
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Efficient annihilation electrochemiluminescence of cationic helicene luminophoresLi, Haidong; Voci, Silvia; Wallabregue, Antoine; Adam, Catherine; ... Sojic, Neso
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Efficient Delivery of Quantum Dots into the Cytosol of Cells Using Cell-Penetrating Poly(disulfide)sDerivery, Emmanuel; Bartolami, Eline; Matile, Stefan; Gonzalez Gaitan, Marcos;
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Electric-Field-Assisted Anion−π CatalysisAkamatsu, Masaaki; Sakai, Naomi; Matile, Stefan;
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Elimination of signals tilting caused by B0 field inhomogeneity using 2D-lineshape reference deconvolutionSheberstov, Kirill; Sinitsyn, Dmitry O.; Cheshkov, Dmitry A.; Jeannerat, Damien;
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Epidithiodiketopiperazines : strain-promoted thiol-mediated cellular uptake at the highest tensionZong, Lili; Bartolami, Eline; Abegg, Daniel; Adibekian, Alexander; ... Matile, Stefan
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Exploring site selectivity of Iridium hydride insertion into allylic alcohols: serendipitous discovery and comparative study of organic and organometallic catalysts for the vinylogous peterson eliminationLi, Houhua; Fiorito, Daniele; Mazet, Clement;
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Human- and computer-accessible 2D correlation data for a more reliable structure determination of organic compoundsJeannerat, Damien;
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Influence of the dissolution solvent on the cytotoxicity of octahedral cationic Ir(III) hydride complexesHuang, Huaiyi; Humbert, Nicolas; Bizet, Vincent; Patra, Malay; ... Gasser, Gilles
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Kinase-templated abiotic reactionSaarbach, Jacques; Lindberg, Eric; Folliet, Sarah; Georgeon, S.; ... Winssinger, Nicolas
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Palladium-Catalyzed Hydrohalogenation of 1,6-Enynes: Hydrogen Halide Salts and Alkyl Halides as Convenient HX SurrogatesPetrone, David A.; Franzoni, Ivan; Ye, Juntao; Rodríguez, José F.; ... Lautens, Mark
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Planarizable push-pull probes : overtwisted flipper mechanophoresMacchione, Mariano; Chuard, Nicolas; Sakai, Naomi; Matile, Stefan;
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Regioselective and Enantiospecific Synthesis of Dioxepines by (Cyclopentadienyl)ruthenium-Catalyzed Condensations of Diazocarbonyls and OxetanesEgger, Leo; Guenee, Laure; Buergi, Thomas; Lacour, Jérôme;
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Rhodium-Catalyzed Enantioselective Isomerization of meso-Oxabenzonorbornadienes to 1,2-Naphthalene OxidesYen, Andy; Choo, Ken-Loon; Yazdi, Shabnam K.; Franke, Patrick T.; ... Lautens, Mark
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Sidechain Engineering in Cell-Penetrating Poly(disulfide)sMorelli, Paola; Matile, Stefan;
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Stereoselective and Enantiospecific Mono- and Bis-C−H Azidation of Tröger Bases : Insight on Bridgehead Iminium Intermediates and Application to Anion-Binding CatalysisBosmani, Alessandro; Pujari, Sandip; Besnard, Céline; Guenee, Laure; ... Lacour, Jérôme
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Strain-Promoted Thiol-Mediated Cellular Uptake of Giant Substrates: Liposomes and PolymersomesChuard, Nicolas; Gasparini, Giulio; Moreau, Dimitri; Lörcher, Samuel; ... Matile, Stefan
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Strained Cyclic Disulfides Enable Cellular Uptake by Reacting with the Transferrin ReceptorAbegg, Daniel; Gasparini, Giulio; Hoch, Dominic Gregor; Shuster, Anton; ... Adibekian, Alexander
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Tight Embrace in a Molecular Knot with Eight CrossingsCougnon, Fabien;
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[4]Helicene-Squalene Fluorescent Nanoassemblies for Specific Targeting of Mitochondria in Live-Cell ImagingBabic, Andréj; Pascal, Simon; Duwald, Romain; Moreau, Dimitri; ... Allémann, Eric

Book Chapters

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Analysis of the Phases of Signals in Two-Dimensional NMRJeannerat, Damien;

Doctoral Thesis

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Synthesis, late-stage functionalization and properties of cationic [6]helicenes chromophoresLabrador Beltran, Maria Géraldine;

2016

Scientific Articles

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A novel HSP90 inhibitor with reduced hepatotoxicity synergizes with radiotherapy to induce apoptosis, abrogate clonogenic survival, and improve tumor control in models of colorectal cancerKinzel, Linda; Ernst, Anne; Orth, Michael; Albrecht, Valerie; ... Lauber, Kirsten
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A ratiometric luminescent switch based on platinum complexes tethered to a crown-ether scaffoldSinn, Stephan; Biedermann, Frank; Vishe, Mahesh; Aliprandi, Alessandro; ... De Cola, Luisa
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Activation of Cell-Penetrating Peptides with Ionpair−π Interactions and FluorophilesChuard, Nicolas; Fujisawa, Kaori; Morelli, Paola; Saarbach, Jacques; ... Matile, Stefan
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Allosterically Regulated Phosphatase Activity from Peptide-PNA Conjugates Folded Through HybridizationMachida, Takuya; Dutt, Som; Winssinger, Nicolas;
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Anion Transport with Chalcogen BondsBenz, Sebastian; Macchione, Mariano; Verolet, Quentin; Mareda, Jiri; ... Matile, Stefan
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Anion-π Catalysis of Enolate Chemistry: Rigidified Leonard Turns as a General Motif to Run Reactions on Aromatic SurfacesCotelle, Yoann; Benz, Sebastian; Avestro, Alyssa-Jennifer; Ward, Thomas R.; ... Matile, Stefan
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Anion-π EnzymesCotelle, Yoann; Lebrun, Vincent; Sakai, Naomi; Ward, Thomas R.; Matile, Stefan
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Asymmetric Anion-π Catalysis on PerylenediimidesWang, Chao; Miros, François; Mareda, Jiri; Sakai, Naomi; Matile, Stefan
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Asymmetric Anion−π Catalysis of Iminium/Nitroaldol Cascades To Form Cyclohexane Rings with Five Stereogenic Centers Directly on π-Acidic SurfacesLiu, Le; Cotelle, Yoann; Avestro, Alyssa-Jennifer; Sakai, Naomi; Matile, Stefan
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Catalytic Enantioselective Total Synthesis of Riccardiphenol BCottet, Pierre; Bleschke, Christian Alexander; Guiteras Capdevila, Montserrat; Tissot, Matthieu; Alexakis, Alexandre
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Characterization of Dimethylsulfoxide / Glycerol Mixtures: A Binary Solvent System for the Study of "Friction-Dependent" Chemical ReactivityAngulo Nunez, Gonzalo Manuel; Brucka, Anna; Gerecke, Mario; Grampp, Günter; ... Wnuk, Paweł
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Chemoproteomics-Enabled Discovery of a Potent and Selective Inhibitor of the DNA Repair Protein MGMTWang, Chao; Abegg, Daniel; Hoch, Dominic Gregor; Adibekian, Alexander;
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Computational Study on the Mechanism of the Palladium-Catalyzed Arylation of α,β-Unsaturated AldehydesFranzoni, Ivan; Poblador Bahamonde, Amalia Isabel;
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Configurationally Stable Doubly Bridged Biphenyl Azocines through Copper-Catalyzed Double Carbene Insertions into the Corresponding AzepinesHarthong, Steven; Brun, Elodie; Grass, Stéphane; Besnard, Céline; ... Lacour, Jérôme
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Copper-Catalyzed Enantioselective Conjugate Addition to α,β-Unsaturated Aldehydes with Various Organometallic ReagentsContal, Sylvie; Gremaud, Ludovic; Palais, Laetitia; Babel, Lucille; Alexakis, Alexandre
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Core-Substituted Naphthalenediimides: LUMO Levels Revisited, in Comparison with Preylenediimides with Sulfur Redox Switches in the CoreMiros, François; Matile, Stefan;
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Cutting Edge Chemical Biology: Report from the 2016 International Symposium on Chemical Biology, January 13–15, Geneva, SwitzerlandAdibekian, Alexander; Stallforth, Pierre;
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Cysteine-specific Chemical Proteomics: From Target Identification to Drug DiscoveryHoch, Dominic Gregor; Abegg, Daniel; Wang, Chao; Shuster, Anton; Adibekian, Alexander
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Dipolar Photosystems: Engineering Oriented Push-Pull Components into Double- and Triple-Channel Surface ArchitecturesBolag, Alatengbaolige; Sakai, Naomi; Matile, Stefan;
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Direct Access to Furoindolines by Palladium-Catalyzed Intermolecular CarboaminationBizet, Vincent; Borrajo Calleja, Gustavo; Besnard, Céline; Mazet, Clement;
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Direct Organocatalysed Double Michael Addition of α-Angelica Lactone to EnonesLagoutte, Roman; Besnard, Céline; Alexakis, Alexandre;
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Discrimination of hexabromocyclododecane from new polymeric brominated flame retardant in polystyrene foam by nuclear magnetic resonanceJeannerat, Damien; Pupier, Marion; Schweizer, Sébastien; Mitrev, Yavor Nikolaev; ... Kohler, Marcel
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Divergent synthesis and identification of the cellular targets of deoxyelephantopinsLagoutte, Roman; Serba, Christelle; Abegg, Daniel; Hoch, Dominic Gregor; ... Winssinger, Nicolas
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Duplex formation and secondary structure of γ-PNA observed by NMR and CDViéville, J.M.P.; Barluenga Badiola, Sofia; Winssinger, Nicolas; Delsuc, M.A.;
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Engineering Protein Self-Assembly: A New Approach for the Design of Octahedral CagesCougnon, Fabien;
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Ethynyl benziodoxolones: functional terminators for cell-penetrating poly(disulfide)sMorelli, Paola; Martin Benlloch, Xavier; Tessier, Romain; Waser, Jérôme; ... Matile, Stefan
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Expanded Chiral Surfaces for Asymmetric Anion–π CatalysisAkamatsu, Masaaki; Matile, Stefan;
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Functionalized cationic [4]helicenes with unique tuning of absorption, fluorescence and chiroptical properties up to the far-red rangeHernandez Delgado, Irene; Pascal, Simon; Wallabregue, Antoine; Duwald, Romain; ... Lacour, Jérôme
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Headgroup engineering in mechanosensitive membrane probesSoleimanpour, Saeideh; Colom Diego, Adai; Derivery, Emmanuel; Gonzalez Gaitan, Marcos; ... Matile, Stefan
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Helicenes : A New Class of Organic Spin FilterKiran, Vankayala; Mathew, Shinto P.; Cohen, Sidney R.; Hernandez Delgado, Irene; ... Naaman, Ron
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High Spatial Resolution Imaging of Endogenous Hydrogen Peroxide in Living Cells by Solid-State FluorescenceLindberg, Eric; Winssinger, Nicolas;
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High-Performance Liquid Chromatographic Resolution of Neutral and Cationic Hetero[6]HelicenesLabrador Beltran, Maria Géraldine; Bosson, Johann; Breitbach, Zachary S.; Lim, Yeeun; ... Lacour, Jérôme
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Interfacing Functional SystemsCotelle, Yoann; Chuard, Nicolas; Lascano, Santiago; Lebrun, Vincent; ... Matile, Stefan
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Iridium-Catalyzed Selective Isomerization of Primary Allylic AlcoholsLi, Houhua; Mazet, Clement;
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Kinetics of Rh(II)-Catalyzed α-Diazo-β-ketoester Decomposition and Application to the [3+6+3+6] Synthesis of Macrocycles on Large Scale and Low Catalyst LoadingsPoggiali, Daniele; Homberg, Alexandre; Lathion, Timothee; Piguet, Claude; Lacour, Jérôme
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New biphenyl iminium salt catalysts for highly enantioselective asymmetric epoxidation: role of additional substitution and dihedral angleBulman Page, Philip C.; Bartlett, Christopher J.; Chan, Yohan; Allin, Steven M.; ... Jones, Garth A.
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NMR analysis of weak molecular interactions using slice-selective experiments via study of concentration gradients in agar gelsMitrev, Yavor Nikolaev; Simova, Svetlana; Jeannerat, Damien;
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Novel PTP1B inhibitors identified by DNA display of fragment pairsBarluenga Badiola, Sofia; Zambaldo, Claudio; Ioannidou, Heraklidia A.; Ciobanu, Mihai; ... Winssinger, Nicolas
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Nucleic Acid Templated Chemical Reaction in a Live VertebrateHoltzer, Laurentius Henricus; Oleinich, Igor; Anzola, Marcello; Lindberg, Eric; ... Winssinger, Nicolas
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One-Step Derivatization of Reducing Oligosaccharides for Rapid and Live-Cell Compatible Chelation-Assisted CuAAC ConjugationMachida, Takuya; Winssinger, Nicolas;
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Palladium-Catalyzed Enantioselective Intermolecular Carboetherification of DihydrofuransBorrajo Calleja, Gustavo; Bizet, Vincent; Mazet, Clement;
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Palladium-Catalyzed Long-Range Deconjugative Isomerization of Highly Substituted α,β-Unsaturated Carbonyl CompoundsLin, Luqing; Romano, Ciro; Mazet, Clement;
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Physicochemical and Electronic Properties of Cationic [6]Helicenes: from Chemical and Electrochemical Stabilities to Far-Red (Polarized) LuminescenceBosson, Johann; Labrador Beltran, Maria Géraldine; Pascal, Simon; Miannay, François-Alexandre; ... Lacour, Jérôme
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Potassium ion-selective fluorescent and pH independent nanosensors based on functionalized polyether macrocyclesJarolimova, Zdenka; Vishe, Mahesh; Lacour, Jérôme; Bakker, Eric;
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Rapid and Scalable Synthesis of cis-Fused Guaiane-Type SesquiterpenesSerba, Christelle; Lagoutte, Roman; Winssinger, Nicolas;
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Regioselective Synthesis and Characterization of Multinuclear Convex-Bound Ruthenium-[n]Cycloparaphenylene (n]Cycloparaphenylene (n=5 and 6) ComplexesKayahara, Eiichi; Patel, Vijay Kumar; Mercier, Audrey Catherine Marie; Kundig, Ernst Peter; Yamago, Shigeru
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Ruthenium Lewis Acid-Catalyzed Asymmetric Diels-Alder Reactions: Reverse-Face Selectivity for α,β-Unsaturated Aldehydes and KetonesThamapipol, Sirinporn; Ludwig, Bettina; Besnard, Céline; Saudan, Christophe; Kundig, Ernst Peter
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Screening for covalent inhibitors using DNA-display of small molecule libraries functionalized with cysteine reactive moietiesZambaldo, Claudio; Daguer, Jean Pierre; Saarbach, Jacques; Barluenga Badiola, Sofia; Winssinger, Nicolas
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Selective Imaging of Late Endosomes with a pH-Sensitive Diazaoxatriangulene Fluorescent ProbeWallabregue, Antoine; Moreau, Dimitri; Sherin, Petr; Moneva Lorente, Pau; ... Lacour, Jérôme
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Surveying the Delivery Methods of CRISPR/Cas9 for ex vivo Mammalian Cell EngineeringKelton, William J.; Pesch, Theresa; Matile, Stefan; Reddy, Sai T.;
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Synthesis of Pyrrolidines and Pyrrolizidines with α-Pseudoquaternary Centers by Copper-Catalyzed Condensation of α-Diazodicarbonyl Compounds and Aryl γ-LactamsGoudedranche, Sébastien; Besnard, Céline; Egger, Leo; Lacour, Jérôme;
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Synthesis of Spiro Ketals, Orthoesters, and Orthocarbonates by CpRu-Catalyzed Decomposition of α-Diazo-β-ketoestersTortoreto, Cecilia; Achard, Thierry; Egger, Leo; Guenee, Laure; Lacour, Jérôme
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The diastereoselective synthesis of octahedral cationic iridium hydride complexes with a stereogenic metal centreHumbert, Nicolas; Mazet, Clement;
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The third orthogonal dynamic covalent bondLascano, Santiago; Zhang, Kangda; Wehlauch, Robin; Gademann, Karl; ... Matile, Stefan
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Unorthodox Interactions at WorkZhao, Yingjie; Cotelle, Yoann; Sakai, Naomi; Matile, Stefan;
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Zwitterionic [4]helicene: a water-soluble and reversible pH-triggered ECD/CPL chiroptical switch in the UV and red spectral regionsPascal, Simon; Besnard, Céline; Zinna, Francesco; Di Bari, Lorenzo; ... Lacour, Jérôme

Book Chapters

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Functionalization of Arenes via C ─H Bond Activation Catalysed by Transition Metal Complexes: Synergy between Experiment and TheoryPoblador Bahamonde, Amalia Isabel;
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Organometallic Complexes of IridiumLi, Houhua; Mazet, Clement; Aitken, R. Alan; Nielsen, Mogens Brønsted; ... Wirth, Thomas

Doctoral Thesis

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Complex surface architectures: the discovery of the third orthogonal dynamic covalent bondLascano, Santiago;
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Mechanistic investigations and development of Rh(II)-catalyzed [3+6+3+6] macrocyclization reactionsPoggiali, Daniele;

2015

Scientific Articles

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1D NMR Homodecoupled 1H Spectra with Scalar Coupling Constants from 2D NemoZS-DIAG ExperimentsCotte, Axelle; Jeannerat, Damien;
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A general Pd-catalyzed α- and γ-benzylation of aldehydes for the formation of quaternary centersFranzoni, Ivan; Guenee, Laure; Mazet, Clement;
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A Mild and Efficient CH2-Extrusion Reaction for the Enantiospecific Synthesis of Highly Configurationally Stable Tröger BasesPujari, Sandip A.; Besnard, Céline; Buergi, Thomas; Lacour, Jérôme;
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Access to enantioenriched 2,3- and 2,5-dihydrofurans with a fully substituted C2 stereocenter by Pd-catalyzed asymmetric intermolecular Heck reactionBorrajo Calleja, Gustavo; Bizet, Vincent; Buergi, Thomas; Mazet, Clement;
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Asymmetric Anion-π Catalysis: Enamine Addition to Nitroolefins on π-Acidic SurfacesZhao, Yingjie; Cotelle, Yoann; Avestro, Alyssa-Jennifer; Sakai, Naomi; Matile, Stefan
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Asymmetric Bromine-Lithium Exchange: Application toward the Synthesis of New Biaryl-Diphosphine LigandsGraff, Julien; Lastawiecka, Elzbieta; Guenee, Laure; Leroux, Frederick; Alexakis, Alexandre
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Asymmetric bromine–lithium exchange: on the importance of both the diamine ligand and the organolithium reagentPraz, Jezabel; Graff, Julien; Egger, Leo; Guenee, Laure; ... Alexakis, Alexandre
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Big, Strong, Neutral, Twisted, and Chiral π AcidsZhao, Yingjie; Huang, Guangxi; Besnard, Céline; Mareda, Jiri; ... Matile, Stefan
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Catalyst-Directed Diastereoselective Isomerization of Allylic Alcohols for the Stereoselective Construction of C(20) in Steroid Side Chains: Scope and Topological DiversificationLi, Houhua; Mazet, Clement;
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