Département de chimie physique

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2019

Scientific Articles

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Amplified vibrational circular dichroism as a manifestation of the interaction between a water soluble gold nanocluster and cobalt saltBhattacharya, Sarita; Buergi, Thomas;
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Anion Transport with Pnictogen Bonds in Direct Comparison with Chalcogen and Halogen BondsLee, Lucia M.; Tsemperouli, Maria; Poblador Bahamonde, Amalia Isabel; Benz, Sebastian; ... Matile, Stefan
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Black Lipid Membranes: Challenges in Simultaneous Quantitative Characterization by Electrophysiology and Fluorescence MicroscopyTsemperouli, Maria; Amstad, Esther; Sakai, Naomi; Matile, Stefan; Sugihara, Kaori
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Doping of thiolate protected gold clusters through reaction with metal surfacesKazan, Rania; Mueller, Ulrich Patrick; Buergi, Thomas;
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Effect of symmetric and asymmetric substitution on the optoelectronic properties of 9,10-dicyanoanthraceneGlöcklhofer, Florian; Rosspeintner, Arnulf; Pasitsuparoad, Pakorn; Eder, Simon; ... Plasser, Felix
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Ground-State Structural Disorder and Excited-State Symmetry Breaking in a Quadrupolar MoleculeSoederberg, Carl Magnus; Dereka, Bogdan; Marrocchi, Assunta; Carlotti, Benedetta; Vauthey, Eric
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Halogen-Bond Assisted Photoinduced Electron TransferDereka, Bogdan; Fureraj, Ina; Rosspeintner, Arnulf; Vauthey, Eric;
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Ion-Pair Dynamics upon Photoinduced Electron Transfer Monitored by Pump–Pump–Probe SpectroscopyBeckwith, Joseph; Lang, Bernhard Felix; Grilj, Jakob; Vauthey, Eric;
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Magnetic field effect on ion pair dynamics upon bimolecular photoinduced electron transfer in solutionFeskov, Serguei V.; Rogozina, Marina V.; Ivanov, Anatoly I.; Aster, Alexander; ... Vauthey, Eric
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Stereochemical significance of O to N atom interchanges within cationic helicenes: experimental and computational evidence of near racemization to remarkable enantiospecificityLabrador Beltran, Maria Géraldine; Besnard, Céline; Buergi, Thomas; Poblador Bahamonde, Amalia Isabel; ... Lacour, Jérôme
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Structural dynamics of an excited donor–acceptor complex from ultrafast polarized infrared spectroscopy, molecular dynamics simulations, and quantum chemical calculationsRumble, Christopher Allen; Vauthey, Eric;
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Towards efficient initiators for two-photon induced polymerization: fine tuning of the donor/acceptor propertiesHolzer, Brigitte; Lunzer, Markus; Rosspeintner, Arnulf; Licari, Giuseppe Léonardo; ... Fröhlich, Johannes
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Transformation from [Au25(SCH2CH2CH2CH3)18]0 to Au28(SCH2CH(CH3)Ph)21 gold nanoclusters: gentle conditions is enoughWang, Yanan; Nieto Ortega, Belen; Buergi, Thomas;
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Tuning symmetry breaking charge separation in perylene bichromophores by conformational controlAster, Alexander; Licari, Giuseppe Léonardo; Zinna, Francesco; Brun, Elodie; ... Vauthey, Eric

Doctoral Thesis

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Atomically precise metal cluster building blocksSels, Annelies;
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Characterisation of polydiacetylene for the detection of forces in membranesOrtuso, Roberto Diego;
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Development of a New closo-Borate Solid Electrolyte and Its Implementation in All-Solid-State BatteriesDuchene, Léo;
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Development of Frozen-Density Embedding theory methods with correlated wavefunctionsZech, Alexander;
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Investigating photoinduced charge-Transfer products using ultrafast spectroscopyBeckwith, Joseph;
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Raman optical activity of small diameter semiconducting single-walled carbon nanotubesMagg, Martin;
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Self-assembled nanostructures for applications in plasmonic metamaterialsGrillo, Rossella;

2018

Scientific Articles

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Cyclopeptidic photosensitizer prodrugs as proteolytically triggered drug delivery systems of pheophorbide A: part I – self-quenched prodrugsBouilloux, Jordan; Yuschenko, Oleksandr; Dereka, Bogdan; Boso, Gianluca; ... Lange, Norbert
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Cyclopeptidic photosensitizer prodrugs as proteolytically triggered drug delivery systems of pheophorbide A: part II – co-loading of pheophorbide A and black hole quencherBouilloux, Jordan; Yuschenko, Oleksandr; Dereka, Bogdan; Boso, Gianluca; ... Lange, Norbert
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Detailed Study on the Failure of the Wedge Calibration Method at Nanonewton Setpoints for Friction Force MicroscopyOrtuso, Roberto Diego; Sugihara, Kaori;
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Detecting order and lateral pressure at biomimetic interfaces using a mechanosensitive second-harmonic-generation probeLicari, Giuseppe Léonardo; Beckwith, Joseph; Soleimanpour, Saeideh; Matile, Stefan; Vauthey, Eric
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Energy transfer and charge separation dynamics in photoexcited pyrene–bodipy molecular dyadsFakis, M.; Beckwith, Joseph; Seintis, Konstantinos; Martinou, E.; ... Vauthey, Eric
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Excimer-Based On-Off Bis(pyreneamide) Macrocyclic ChemosensorsVishe, Mahesh; Lathion, Timothee; Pascal, Simon; Yushchenko, Oleksandr; ... Lacour, Jérôme
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Excited-state dynamics of a molecular dyad with two orthogonally-oriented fluorophoresLetrun, Romain; Lang, Bernhard Felix; Yushchenko, Oleksandr; Wilcken, Roland; ... Vauthey, Eric
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Highly Stable and Red-Emitting Nanovesicles Incorporating Lipophilic Diketopyrrolopyrroles for Cell ImagingArdizzone, Antonio; Blasi, Davide; Vona, Danilo; Rosspeintner, Arnulf; ... Veciana, Jaume
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Influence of the hydrogen-bond interactions on the excited-state dynamics of a push–pull azobenzene dye: the case of Methyl OrangeNancoz, Christoph; Licari, Giuseppe Léonardo; Beckwith, Joseph; Soederberg, M; ... Vauthey, Eric
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Machine Learning for Analysis of Time-Resolved Luminescence DataĐorđević, Nikola; Beckwith, Joseph; Yarema, Maksym; Yarema, Olesya; ... Wood, Vanessa
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Mechanosensitive Oligodithienothiophenes: Transmembrane Anion Transport Along Chalcogen-Bonding CascadesMacchione, Mariano; Tsemperouli, Maria; Goujon, Antoine; Mallia, Ajith; ... Matile, Stefan
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Membrane bound COMT isoform is an interfacial enzyme: general mechanism and new drug design paradigmMagarkar, Aniket; Parkkila, Petteri; Viitala, Tapani; Lajunen, Tatu; ... Bunker, Alex
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More than a Solvent: Donor–Acceptor Complexes of Ionic Liquids and Electron AcceptorsAster, Alexander; Vauthey, Eric;
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Optical transient absorption experiments reveal the failure of formal kinetics in diffusion assisted electron transfer reactionsAngulo, Gonzalo; Rosspeintner, Arnulf; Lang, Bernhard Felix; Vauthey, Eric;
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Photolabile coumarins with improved efficiency through azetidinyl substitutionBassolino, Giovanni; Nancoz, Christoph; Thiel, Zacharias; Bois, Estelle Marine; ... Rivera-Fuentes, Pablo
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Salt Effect in Ion-Pair Dynamics after Bimolecular Photoinduced Electron Transfer in a Room-Temperature Ionic LiquidRosspeintner, Arnulf; Koch, Marius; Angulo Nunez, Gonzalo Manuel; Vauthey, Eric;
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Size extensivity of elastic properties of alkane fragmentsRadiom, Milad; Maroni, Plinio; Wesolowski, Tomasz Adam;
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Synergistic Anion–(π)n–π Catalysis on π-Stacked FoldamersBornhof, Anna-Bea; Bauza, Antonio; Aster, Alexander; Pupier, Marion; ... Matile, Stefan
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Thermodynamic Programming of Erbium(III) Coordination Complexes for Dual Visible/Near-Infrared LuminescenceGolesorkhi, Bahman; Guenee, Laure; Nozary, Homayoun; Fuerstenberg, Alexandre; ... Piguet, Claude
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Transient Glass Formation around a Quadrupolar Photoexcited Dye in a Strongly H-Bonding Liquid Observed by Transient 2D-IR SpectroscopyDereka, Bogdan; Helbing, Jan; Vauthey, Eric;
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Ultrafast excited state decay of natural UV filters: from intermolecular hydrogen bonds to a conical intersectionSherin, Petr; Tsentalovich, Yuri P.; Vauthey, Eric; Benassi, Enrico;
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Wavelength-optimized Two-Photon Polymerization Using Initiators Based on Multipolar Aminostyryl-1,3,5-triazinesTromayer, Maximilian; Gruber, Peter; Rosspeintner, Arnulf; Ajami, Aliasghar; ... Liska, Robert
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White-Fluorescent Dual-Emission Mechanosensitive Membrane Probes that Function by Bending Rather than TwistingHumeniuk, Heorhii; Rosspeintner, Arnulf; Licari, Giuseppe Léonardo; Kilin, Vasyl; ... Matile, Stefan

Doctoral Thesis

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Black lipid membranes: investigation of their properties and their application in the characterization of active membrane componentsTsemperouli, Maria;
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Excited-state symmetry breaking: from fundamental photophysics to asymmetrical photochemistryDereka, Bogdan;
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Second harmonic generation applied to biomimetic interfacesLicari, Giuseppe Léonardo;

2017

Scientific Articles

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A biocompatible macromolecular two-photon initiator based on hyaluronanTromayer, Maximilian; Gruber, Peter; Markovic, Marica; Rosspeintner, Arnulf; ... Liska, Robert
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A highly stable sodium solid-state electrolyte based on a dodeca/deca-borate equimolar mixtureDuchene, Léo; Kühnel, R.-S.; Rentsch, D.; Remhof, Arndt; ... Battaglia, Corsin
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A Simple Approach for Predicting the Spin State of Homoleptic Fe(II) Tris-diimine ComplexesPhan, Hoa; Hrudka, Jeremy J.; Igimbayeva, Dilyara; Lawson Daku, Latevi Max; Shatruk, Michael
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A simple model of solvent-induced symmetry-breaking charge transfer in excited quadrupolar moleculesIvanov, Anatoly I.; Dereka, Bogdan; Vauthey, Eric;
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An alternative approach to the synthesis of NaB3H8 and Na2B12H12 for solid electrolyte applicationsMoury, Romain Yves; Gigante, Angelina; Hagemann, Hans-Rudolf;
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Artificial tubular connections between cells based on synthetic lipid nanotubesKozintsev, Alexander; Sugihara, Kaori;
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Au38Cu1(2-PET)24 nanocluster: synthesis, enantioseparation and luminescenceKazan, Rania; Zhang, Bei; Buergi, Thomas;
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Cluster evolution in molecular three-dimensional spin-crossover systemsStoleriu, Laurentiu; Nishino, Masamichi; Miyashita, Seiji; Stancu, Alexandru; ... Enachescu, Cristian
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Computational study of the vibrational spectroscopy properties of boron-hydrogen compounds: Mg(B3H8)2, CB9H10 and CB11H12Sethio, Daniel; Lawson Daku, Latevi Max; Hagemann, Hans-Rudolf;
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Controlling Lanthanide Exchange in Triple-Stranded Helicates: A Way to Optimize Molecular Light-UpconversionZare, Davood; Suffren, Yan Jonathan Mathieu; Nozary, Homayoun; Hauser, Andreas; Piguet, Claude
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Cr-substitution in Ba2In2O5·(H2O)x (x = 0.16, 0.74)Yoon, Songhak; Son, Kwanghyo; Hagemann, Hans-Rudolf; Widenmeyer, Marc; Weidenkaff, Anke
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Direct local solvent probing by transient infrared spectroscopy reveals the mechanism of hydrogen-bond induced nonradiative deactivationDereka, Bogdan; Vauthey, Eric;
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Enantiospecific Elongation of Cationic Helicenes by Electrophilic Functionalization at Terminal EndsDuwald, Romain; Pascal, Simon; Bosson, Johann; Grass, Stéphane; ... Lacour, Jérôme
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Exploring Fluorescent Dyes at Biomimetic Interfaces with Second Harmonic Generation and Molecular DynamicsLicari, Giuseppe Léonardo; Cwiklik, Lukasz; Jungwirth, Pavel; Vauthey, Eric;
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Fluoride substitution in LiBH4; destabilization and decompositionRichter, Bo; Ravnsbæk, Dorthe B.; Sharma, Manish; Spyratou Stratmann, Alexandra; ... Jensen, Torben R.
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How good is the generalized Langevin equation to describe the dynamics of photo-induced electron transfer in fluid solution?Angulo, Gonzalo; Jedrak, Jakub; Ochab-Marcinek, Anna; Pasitsuparoad, Pakorn; ... Rosspeintner, Arnulf
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Implementation and Application of the Frozen Density Embedding Theory with the Algebraic Diagrammatic Construction Scheme for the Polarization Propagator up to Third OrderPrager, Stefan; Zech, Alexander; Wesolowski, Tomasz Adam; Dreuw, Andreas;
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Influence of Solvent Relaxation on Ultrafast Excited-State Proton Transfer to SolventKumpulainen, Tatu Samuli; Rosspeintner, Arnulf; Dereka, Bogdan; Vauthey, Eric;
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Kinetic Resolution of 2-Substituted Indolines by N-Sulfonylation using an Atropisomeric 4-DMAP-N-oxide OrganocatalystMurray, James I.; Flodén, Nils J.; Bauer, Adriano; Fessner, Nico D.; ... Spivey, Alan C.
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Looking at Photoinduced Charge Transfer Processes in the IR: Answers to Several Long-Standing QuestionsDereka, Bogdan; Koch, Marius; Vauthey, Eric;
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Mapping Infrared Enhancement around Gold Nanoparticles Using PolyelectrolytesGhosh, Harekrishna; Buergi, Thomas;
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Mechanosensitivity of polydiacetylene with a phosphocholine headgroupOrtuso, Roberto Diego; Cataldi, Ugo; Sugihara, Kaori;
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Original oxo-centered bismuth oxo-arsenates; critical effect of PO4 for AsO4 substitutionOlchowka, Jacob; Colmont, M.; Aliev, A.; Tran, T. Thao; ... Mentré, O.
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Probe dependence on polar solvation dynamics from fs broadband fluorescenceKumpulainen, Tatu Samuli; Rosspeintner, Arnulf; Vauthey, Eric;
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Reorientational Hydrogen Dynamics in Complex Hydrides with Enhanced Li+ ConductionBurankova, Tatsiana; Duchene, Léo; Łodziana, Zbigniew; Frick, Bernhard; ... Embs, Jan P.
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Search for Electron Delocalization from [Fe(CN)6]3- to the Dication of Viologen in (DNP)3[Fe(CN)6]2 · 10H2OAbouelwafa, Ahmed; Hauser, Andreas; Mereacre, Valeriu; Lan, Yanhua; ... Powell, Annie K.
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Simulations of the Ultrafast Transient Absorption Dynamics of a Donor–Acceptor Biaryl in SolutionFedunov, Roman G.; Plotnikova, Anastasiia V.; Ivanov, Anatoly I.; Vauthey, Eric;
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Solute–Solvent Interactions and Excited-State Symmetry Breaking: Beyond the Dipole–Dipole and the Hydrogen-Bond InteractionsDereka, Bogdan; Vauthey, Eric;
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Specific Monitoring of Excited-State Symmetry Breaking by Femtosecond Broadband Fluorescence Upconversion SpectroscopyBeckwith, Joseph S.; Rosspeintner, Arnulf; Licari, Giuseppe Léonardo; Lunzer, Markus; ... Vauthey, Eric
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Structural Investigation of the Ligand Exchange Reaction with Rigid Dithiol on Doped (Pt, Pd) Au25 ClustersSels, Annelies; Salassa, Giovanni; Pollitt, Stephan; Guglieri, Clara; ... Buergi, Thomas
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Triggering Emission with the Helical Turn in Thiadiazole-HelicenesBiet, Thomas; Martin, Kévin; Hankache, Jihane; Hellou, Nora; ... Avarvari, Narcis
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Triplet state CPL active helicene–dithiolene platinum bipyridine complexesBiet, Thomas; Cauchy, Thomas; Sun, Qinchao; Ding, Jie; ... Avarvari, Narcis
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Ultrafast Elementary Photochemical Processes of Organic Molecules in Liquid SolutionKumpulainen, Tatu Samuli; Lang, Bernhard Felix; Rosspeintner, Arnulf; Vauthey, Eric;
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Ultrafast transient IR spectroscopy and DFT calculations of ruthenium(II) polypyridyl complexesSun, Qinchao; Dereka, Bogdan; Vauthey, Eric; Lawson Daku, Latevi Max; Hauser, Andreas

Doctoral Thesis

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Computing excited state properties of chromophores: a challenge for the computational chemistHumbert-Droz, Marie;
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Critical evaluation of the effect of anharmonicity and dispersion interactions using density functional theory on structural and spectroscopic properties of selected inorganic compoundsSethio, Daniel;
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Excited-state dynamics in electron-donor-acceptor systems of increasing complexityYushchenko, Oleksandr;
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Experimental and theoretical studies of boron and hydrogen containing compounds in relation to potential hydrogen storage and ionic conduction applicationsSharma, Manish;
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Structural investigation of the High-Spin→Low-Spin relaxation dynamics in spin crossover compoundsDelgado Perez, Maria Teresa;

2016

Scientific Articles

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A theoretical study of the spectroscopic properties of B2H6 and of a series of BxHyz- species (x = 1-12, y = 3-14, z = 0-2): From BH3 to B12H122-Sethio, Daniel; Lawson Daku, Latevi Max; Hagemann, Hans-Rudolf;
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Characterization of Dimethylsulfoxide / Glycerol Mixtures: A Binary Solvent System for the Study of "Friction-Dependent" Chemical ReactivityAngulo Nunez, Gonzalo Manuel; Brucka, Anna; Gerecke, Mario; Grampp, Günter; ... Wnuk, Paweł
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Combined Electrical and Optical Characterization of PolydiacetyleneGirard-Reydet, Clement; Ortuso, Roberto Diego; Tsemperouli, Maria; Sugihara, Kaori;
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Comment on "Observation of the Marcus Inverted Region for Bimolecular Photoinduced Electron-Transfer Reactions in Viscous Media"Angulo Nunez, Gonzalo Manuel; Rosspeintner, Arnulf; Koch, Marius; Vauthey, Eric;
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Configurationally Stable Doubly Bridged Biphenyl Azocines through Copper-Catalyzed Double Carbene Insertions into the Corresponding AzepinesHarthong, Steven; Brun, Elodie; Grass, Stéphane; Besnard, Céline; ... Lacour, Jérôme
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Control of the plasmonic resonance of a graphene coated plasmonic nanoparticle array combined with a nematic liquid crystalDe Sio, Luciano; Cataldi, Ugo; Buergi, Thomas; Tabiryan, Nelson; Bunning, Timothy J.
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Cooperative enhancement versus additivity of two-photon-absorption cross sections in linear and branched squaraine superchromophoresCeymann, Harald; Rosspeintner, Arnulf; Schreck, Maximilian H.; Mützel, Carina; ... Lambert, Christoph
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Direct Visualization of Excited-State Symmetry Breaking Using Ultrafast Time-Resolved Infrared SpectroscopyDereka, Bogdan; Rosspeintner, Arnulf; Li, Zhiquan; Liska, Robert; Vauthey, Eric
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Directional Energy Transfer in Nanocrystals of [Ru(2,2′-bipyridine)3]­[NaCr(oxalate)3]Previtera, Elia; Tissot, Antoine Michel; Hauser, Andreas;
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