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Catalytic Enantioselective Total Synthesis of Riccardiphenol B Cottet, Pierre; Bleschke, Christian Alexander; Guiteras Capdevila, Montserrat; Tissot, Matthieu; Alexakis, Alexandre 2016
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Copper-Catalyzed Enantioselective Conjugate Addition to α,β-Unsaturated Aldehydes with Various Organometallic Reagents Contal, Sylvie; Gremaud, Ludovic; Palais, Laetitia; Babel, Lucille; Alexakis, Alexandre 2016
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Direct Organocatalysed Double Michael Addition of α-Angelica Lactone to Enones Lagoutte, Roman; Besnard, Céline; Alexakis, Alexandre 2016
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Asymmetric bromine–lithium exchange: on the importance of both the diamine ligand and the organolithium reagent Praz, Jezabel; Graff, Julien; Egger, Leo; Guenee, Laure; ... Alexakis, Alexandre 2015
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Copper-Catalyzed Asymmetric Conjugate Addition to α-Alkylidene Cycloalkanones Garcia, Pierre; Germain, Nicolas; Woodward, Simon; Alexakis, Alexandre 2015
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Enantioselective Halogenative Semi-Pinacol Rearrangement: Extension of Substrate Scope and Mechanistic Investigations Romanov Michailidis, Fedor; Romanova Michailidi, Maria; Pupier, Marion; Alexakis, Alexandre 2015
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Formation of Contiguous Quaternary and Tertiary Stereocenters by Sequential Asymmetric Conjugate Addition of Grignard Reagents to 2-Substituted Enones and Mg-Enolate Trapping Germain, Nicolas; Alexakis, Alexandre 2015
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Asymmetric Bromine-Lithium Exchange: Application toward the Synthesis of New Biaryl-Diphosphine Ligands Graff, Julien; Lastawiecka, Elzbieta; Guenee, Laure; Leroux, Frederick; Alexakis, Alexandre 2015
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Improvements and Applications of the Transition Metal-Free Asymmetric Allylic Alkylation using Grignard Reagents and Magnesium Alanates Grassi, David; Alexakis, Alexandre 2015
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Enantioselective 1,4-additions of ClMeAl(CH=CHR) (R = alkyl, alkenyl, Ph) to cyclohexenones Willcox, Darren; Woodward, Simon; Alexakis, Alexandre 2014
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Copper-Catalyzed Asymmetric Conjugate Addition Alexakis, Alexandre; Krause, Norbert; Woodward, Simon 2014
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Copper-Catalyzed Asymmetric Conjugate Addition and Allylic Substitution of Organometallic Reagents to Extended Multiple-Bond Systems Tissot, Matthieu; Li, Hailing; Alexakis, Alexandre 2014
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Copper-Catalyzed Asymmetric Synthesis Alexakis, Alexandre; Krause, Norbert; Woodward, Simon 2014
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Enantioselective halogenative semi-pinacol rearrangement: a stereodivergent reaction on a racemic mixture Romanov Michailidis, Fedor; Pupier, Marion; Guenee, Laure; Alexakis, Alexandre 2014
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Transition metal-free asymmetric and diastereoselective allylic alkylation using Grignard reagents: construction of vicinal stereogenic centers via kinetic resolution Grassi, David; Alexakis, Alexandre 2014
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Asymmetric Conjugate Addition to α-Substituted Enones/Enolate Trapping Germain, Nicolas; Guenee, Laure; Mauduit, Marc; Alexakis, Alexandre 2014
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Direct Organocatalytic Construction of Bicyclo[3.2.1]octanes by Domino Michael/Aldol Reaction with β,γ-Unsaturated 1,2-Keto Amides Lefranc, Alice; Guenee, Laure; Contal, Sylvie; Alexakis, Alexandre 2014
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Copper-Catalyzed Propargylic Substitution of Dichloro Substrates: Enantioselective Synthesis of Trisubstituted Allenes and Formation of Propargylic Quaternary Stereogenic Centers Li, Hailing; Grassi, David; Guenee, Laure; Buergi, Thomas; Alexakis, Alexandre 2014
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Enantioselective Catalytic Fluorinative Aza-semipinacol Rearrangement Romanov Michailidis, Fedor; Pupier, Marion; Besnard, Céline; Buergi, Thomas; Alexakis, Alexandre 2014
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Construction of Bicyclo[3.2.1]octanes with Four Stereogenic Centers by Organocatalytic Domino Michael/Aldol Reaction Lefranc, Alice; Gremaud, Ludovic; Alexakis, Alexandre 2014
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Domino Asymmetric Conjugate Addition–Conjugate Addition Germain, Nicolas; Schlaefli, Dorian; Chellat, Mathieu; Rosset, Stéphane; Alexakis, Alexandre 2014
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Copper-Free Asymmetric Allylic Alkylation of Trisubstituted Cyclic Allyl Bromides Using Grignard Reagents Grassi, David; Alexakis, Alexandre 2013
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Organocatalytic conjugate addition in stereoselective synthesis Quintard, Adrien; Alexakis, Alexandre 2013
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Creation of Highly Congested Quaternary Centers via Cu-catalyzed Conjugate Addition of Alkenyl Alanates to β-Substituted Cyclic Enones Mueller, Daniel; Alexakis, Alexandre 2013
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Highly Diastereo- and Enantioselective Organocatalytic Domino Michael/Aldol Reaction of Acyclic 3-Halogeno-1,2-Diones to α,β-Unsaturated Aldehydes Lefranc, Alice; Guenee, Laure; Alexakis, Alexandre 2013
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Direct Trapping of Sterically Encumbered Aluminum Enolates Bleschke, Christian Alexander; Tissot, Matthieu; Mueller, Daniel; Alexakis, Alexandre 2013
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Organocatalytic Asymmetric Annulation of 1,3-Bis(alkoxycarbonyl)buta-1,3-dienes and Aldehydes Pezzati, Bernardo; Chellat, Mathieu; Murphy, John J.; Besnard, Céline; ... Alexakis, Alexandre 2013
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Asymmetric Bromine–Lithium Exchange: Application toward the Synthesis of Natural Product Graff, Julien; Debande, Thibaut; Praz, Jezabel; Guenee, Laure; Alexakis, Alexandre 2013
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Enantioselective Organocatalytic Fluorination-Induced Wagner-Meerwein Rearrangement Romanov Michailidis, Fedor; Guenee, Laure; Alexakis, Alexandre 2013
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Enantio- and Regioselective Conjugate Addition of Organometallic Reagents to Linear Polyconjugated Nitroolefins Tissot, Matthieu; Alexakis, Alexandre 2013
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Practical Synthesis of SimplePhos Ligands: Further Development of Alkyl-Substituted Phosphanamines Mueller, Daniel; Guenee, Laure; Alexakis, Alexandre 2013
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Enantioselective 1,6-Conjugate Addition of Dialkylzinc Reagents to Acyclic Dienones Catalyzed by Cu-DiPPAM Complex-Extension to Asymmetric Sequential 1,6/1,4-Conjugate Addition Magrez-Chiquet, Magaly; Morin, Marie S. T.; Wencel-Delord, Joanna; Drissi Amraoui, Sammy; ... Mauduit, Marc 2013
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Copper-Free Asymmetric Allylic Alkylation with a Grignard Reagent: Design of the Ligand and Mechanistic Studies Grassi, David; Dolka, Chrysanthi; Jackowski, Olivier; Alexakis, Alexandre 2013
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Copper-Catalyzed Asymmetric Conjugate Addition of Alkenyl- and Alkylalanes to α,β-Unsaturated Lactams Cottet, Pierre; Mueller, Daniel; Alexakis, Alexandre 2013
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Construction of Enantioenriched Cyclic Compounds by Asymmetric Allylic Alkylation and Ring-Closing Metathesis Giacomina, Francesca; Alexakis, Alexandre 2013
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Formation of Quaternary Stereogenic Centers by Copper-Catalyzed Asymmetric Conjugate Addition Reactions of Alkenylaluminums to Trisubstituted Enones Mueller, Daniel; Alexakis, Alexandre 2013
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Enantioselective Organocatalytic Iodination-Initiated Wagner–Meerwein Rearrangement Romanov Michailidis, Fedor; Guenee, Laure; Alexakis, Alexandre 2013
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Enantioselective Copper-Catalyzed Conjugate Addition of Trimethylaluminum to β,γ-Unsaturated α-Ketoamides: Efficient Access to γ-Methyl-Substituted Carbonyl Compounds Contal, Sylvie; Gremaud, Ludovic; Alexakis, Alexandre 2013
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Formation of chiral fluoroalkyl products through copper-free enantioselective allylic alkylation catalyzed by an NHC ligand Grassi, David; Li, Hailing; Alexakis, Alexandre 2012
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Copper-catalyzed Asymmetric Conjugate Addition to Challenging Michael Acceptors and Synthesis of Relevant Target Molecules Gremaud, Ludovic; Palais, Laetitia; Alexakis, Alexandre 2012
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Copper-catalyzed Enantioselective Allylic Substitution Langlois, Jean-Baptiste; Alexakis, Alexandre 2012
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Copper-Catalyzed Asymmetric 1,4-Addition of Alkenyl Alanes to N-Substituted-2-3-dehydro-4-piperidones Mueller, Daniel; Alexakis, Alexandre 2012
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Mechanistic identification and improvement of a direct enantioconvergent transformation in copper-catalyzed asymmetric allylic alkylation Langlois, Jean-Baptiste; Emery, Daniel; Mareda, Jiri; Alexakis, Alexandre 2012
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Furanoside phosphite–phosphoroamidite and diphosphoroamidite ligands applied to asymmetric Cu-catalyzed allylic substitution reactions Magre, Marc; Mazuela, Javier; Diéguez, Montserrat; Pàmies, Oscar; Alexakis, Alexandre 2012
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Rhodium and copper-catalyzed asymmetric conjugate addition of alkenyl nucleophiles Mueller, Daniel; Alexakis, Alexandre 2012
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Enantioselective Copper-Catalyzed Conjugate Addition of Trimethylaluminium to β,γ-Unsaturated α-Ketoesters Gremaud, Ludovic; Alexakis, Alexandre 2012
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Enyne Chlorides: Substrates for Copper-Catalyzed Asymmetric Allylic Alkylation Li, Hailing; Alexakis, Alexandre 2012
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Copper-Free Asymmetric Allylic Alkylation Using Grignard Reagents on Bifunctional Allylic Bromides Grassi, David; Alexakis, Alexandre 2012
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N-Heterocyclic Carbene-Catalyzed Annulation of α-Cyano-1,4-diketones with Ynals Romanov Michailidis, Fedor; Besnard, Céline; Alexakis, Alexandre 2012
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Copper-Catalyzed Enantioselective Synthesis of Axially Chiral Allenes Li, Hailing; Mueller, Daniel; Guenee, Laure; Alexakis, Alexandre 2012
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