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ω-ethylenic allylic substrates as alternatives to cyclic substrates in copper- and iridium-catalyzed asymmetric allylic alkylation Giacomina, Francesca; Riat, David; Alexakis, Alexandre 2010
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γ-Tributylstannyl-β-metallated acrolein : a versatile synthon Marek, Ilane; Alexakis, Alexandre; Normant, Jean F. 1991
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β-Disubstituted Allylic Chloride: Substrate for th Cu-Catalyzed Asymmetric SN2' Reaction Falciola, Caroline Alexandra; Tissot-Croset, Karine; Alexakis, Alexandre 2006
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Z-1-Iodohexene Alexakis, Alexandre; Cahiez, G.; Normant, Jean F. 1984
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Vinylcopper derivatives. XI. Reactivity of Z-alkenylcuprates towards various electrophiles. Application to the synthesis of some natural products Alexakis, Alexandre; Cahiez, Gerard; Normant, Jean F. 1980
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Vinyl-copper reagents 16. Synthesis of conjugated dienes via the addition of vinyl cuprates to acetylene Alexakis, Alexandre; Normant, Jean F. 1982
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Vinyl-copper derivatives. XII. Stereospecific synthesis of allylic amines by aminomethylation of organocopper reagents Germon, C.; Alexakis, Alexandre; Normant, Jean F. 1980
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Vinyl-copper derivatives XIII: Synthesis of conjugated dienes of very high stereoisomeric purity Jabri, N.; Alexakis, Alexandre; Normant, Jean F. 1981
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Vinyl-copper derivatives X. Alkylation of (Z) dialkenylcuprates Alexakis, Alexandre; Cahiez, Gerard; Normant, Jean F. 1979
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Vinyl-copper derivatives 151. An efficient synthesis of polysubstituted conjugated dienes Jabri, N.; Alexakis, Alexandre; Normant, Jean F. 1982
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Very efficient phosphoramidite ligand for asymmetric iridium-catalyzed allylic alkylation Alexakis, Alexandre; Polet, Damien 2004
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Unusually facile palladium catalysed oxidation of imidazolidines and oxazolidines Alexakis, Alexandre; Aujard, Isabelle; Pytkowicz, Julien; Roland, Sylvain; Mangeney, Pierre 2001
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Unusual 1,2-migration in organoaluminium chemistry, promoted by BF3.OEt2 Alexakis, Alexandre; Hanaïzi, Jezia; Jachiet, Denis; Normant, Jean F. 1990
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Ultrasound assisted cleavage of hydrazines by Raney nickel Alexakis, Alexandre; Lensen, Nathalie; Mangeney, Pierre 1991
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Two-step synthesis of homochiral monoaminals of tricarbonylphthalaldehydechromium complex Rose-Munch, Françoise; Gagliardini, Vanessa; Perrotey, Anne; Tranchier, Jean-Philippe; ... Vaissermann, Jacqueline 1999
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Transition metal-free asymmetric and diastereoselective allylic alkylation using Grignard reagents: construction of vicinal stereogenic centers via kinetic resolution Grassi, David; Alexakis, Alexandre 2014
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Titanium induced coupling of imines to symmetrical vicinal (R*,R*)-diamines Mangeney, Pierre; Tejero, T.; Alexakis, Alexandre; Grosjean, F.; Normant, Jean F. 1988
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The use of N-iPr-2,2'-bipyrrolidine derivatives as organocatalysts for asymmetric Michael additions Sulzer Mossé, Sarah; Andrey, Olivier; Alexakis, Alexandre 2006
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The use of N-alkyl-2,2'-bipyrrolidine derivatives as organocatalysts for the asymmetric Michael addition of ketones and aldehydes to nitroolefins Andrey, Olivier; Alexakis, Alexandre; Tomassini, Axel; Bernardinelli, Gérald Hugues 2004
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The hydroalumination of ω-terbutoxy alkynes an easy access to ω-hydroxy alkenyl iodides. Application to the synthesis of dienic insect pheromone Alexakis, Alexandre; Duffault, Jean-Marc 1988
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The copper-catalyzed asymmetric allylic substitution Alexakis, Alexandre; Malan, Christophe; Lea, Louise Sarah; Tissot-Croset, Karine; ... Falciola, Caroline Alexandra 2006
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The conjugate addition reaction Alexakis, Alexandre 2004
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The conjugate addition reaction Alexakis, Alexandre 1998
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Tandem reactions with chiral enolates: preparation of allylic alcohols via trapping with vinyl oxiranes Welker, Matthias; Woodward, Simon; Alexakis, Alexandre 2010
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Tandem enantioselective conjugate addition-electrophile trapping reactions. Application in the formation of syn or anti aldols Alexakis, Alexandre; Trevitt, Graham Peter; Bernardinelli, Gérald Hugues 2001
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Tandem enantioselective conjugate addition-cyclopropanation. Application to natural product synthesis Alexakis, Alexandre; March, Sebastien 2002
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Tandem Copper-catalyzed enantioselective allylation-metathesis Alexakis, Alexandre; Tissot-Croset, Karine 2002
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Tandem asymmetric conjugate addition-silylation of enantiomerically enriched zinc enolates. Synthetic importance and mechanistic implications Knopff, Oliver; Alexakis, Alexandre 2002
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Tandem asymmetric conjugate addition-enolacetates formation of enantiomerically enriched zinc and aluminium enolates Vuagnoux-D'Augustin De, Magali; Alexakis, Alexandre 2007
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TADDOL organophosphorus derivatising agents for the determination of the enantiomeric excess of alcohols and carboxylic acids by 31P and 1H NMR spectroscopy Alexakis, Alexandre; Chauvin, Anne-Sophie 2000
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Synthesis of regioselectively deuterated hydroxy conjugated dienes Duffault, Jean-Marc; Einhorn, Jacques; Alexakis, Alexandre 1995
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Synthesis of (Z,Z)-3,13-octadecadien-1-yl acetate. Component of the sex pheromone of Synanthedon tenuis Gardette, M.; Alexakis, Alexandre; Normant, Jean F. 1983
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Synthesis of (Z)-13-Hexadecen-11-yn-1-yl acetate, major component of the sex pheromone of the Processionary moth Gardette, M.; Alexakis, Alexandre; Normant, Jean F. 1983
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Synthesis and use of a phosphoramidite ligand for the copper-catalyzed enantioselective allylic substitution. Tandem allylic substitution-ring closing metathesis Tissot-Croset, Karine; Polet, Damien; Gille, Segolene; Hawner, Christine; Alexakis, Alexandre 2004
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Synthesis and use of 3,3'-bimorpholine derivatives in asymmetric Michael addition and intramolecular aldol reaction Sulzer Mossé, Sarah; Laars, Marju; Kriis, Kadri; Kanger, Tõnis; Alexakis, Alexandre 2007
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Synthesis and applications of chiral bis-THF in asymmetric synthesis Alexakis, Alexandre; Tomassini, Axel; Leconte, Stéphane 2004
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Synthesis and application of chiral phosphorus ligands derived from TADDOL for the asymmetric conjugate addition of diethylzinc to enones Alexakis, Alexandre; Burton, Jonathan; Vastra, Johann; Benhaim, Cyril; ... Rosset, Stéphane 2000
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Synthesis and application of a new pseudo C2-symmetric tertiary diamine for the enantioselective addition of MeLi to aromatic imines Perron, Quentin; Alexakis, Alexandre 2007
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Synthèse stéréospécifique d'oléfines di- et trisubstituées par alcoylation des vinyl cuivres Normant, Jean F.; Cahiez, Gerard; Chuit, Claude; Alexakis, Alexandre; Villieras, Jean 1972
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Synthèse d'alcoxy-allènes chiraux par carbocupration d'acétals propargyliques. Etude de leur réactivité à l'égard d'organocuprates Marek, Ilane; Alexakis, Alexandre; Mangeney, Pierre; Normant, Jean F. 1992
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Synthèse asymétrique d'aldéhydes à partir d'oxazolidines chirales α,β-insaturées et d'organocuprates Mangeney, Pierre; Alexakis, Alexandre; Normant, Jean F. 1983
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Sugar-based phosphite and phosphoroamidite ligands for the Cu-catalyzedasymmetric 1,4-addition to enones Raluy, Eva; Pàmies, Oscar; Diéguez, Montserrat; Rosset, Stéphane; Alexakis, Alexandre 2009
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Substitution directe de l'halogène d'halohydrines 1-2 par des organomagnésiens et lithiens en présence de sel cuivreux Normant, Jean F.; Mulamba, T.; Scott, F.; Alexakis, Alexandre; Cahiez, Gerard 1978
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Stereochemical effects of trimethylsilyl chloride (TMSCl) on the conjugate addition of organocopper reagents Alexakis, Alexandre; Sedrani, R.; Mangeney, Pierre 1990
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Stereochemical aspects on the formation of chiral allenes from propargylic ethers and epoxides Alexakis, Alexandre 1992
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ß- and γ- disubstituted olefins: susbtrates for copper-catalysed asymmetric allylic substitution Falciola, Caroline Alexandra; Tissot-Croset, Karine; Reyneri, Hugo; Alexakis, Alexandre 2008
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Spiroannelation via gem-dihalocyclopropane substrates and a cyclocuprate species Scott, Federick; Mafunda, Brownlee G.; Normant, Jean F.; Alexakis, Alexandre 1983
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Special topic issue on the theme of organometallics in organic synthesis Alexakis, Alexandre; Kundig, Ernst Peter 2006
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Some aspects of the reactivity of RCu/BF3 reagents towards the ether linkage Alexakis, Alexandre; Mangeney, Pierre; Ghribi, A.; Jachiet, D.; ... Holmes, A.B. 1988
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SimplePhos monodentate ligands: Synthesis and application in copper-catalysed reactions Palais, Laetitia; Mikhel, Igor; Bournaud, Chloee Julie; Micouin, Laurent; ... Alexakis, Alexandre 2007
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