Alexakis, Alexandre

 
 
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2012

Scientific Articles

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Copper-Free Asymmetric Allylic Alkylation Using Grignard Reagents on Bifunctional Allylic BromidesGrassi, David; Alexakis, Alexandre;
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Enantioselective Copper-Catalyzed Conjugate Addition of Trimethylaluminium to β,γ-Unsaturated α-KetoestersGremaud, Ludovic; Alexakis, Alexandre;
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Enyne Chlorides: Substrates for Copper-Catalyzed Asymmetric Allylic AlkylationLi, Hailing; Alexakis, Alexandre;
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Evaluation of the Chiral DIANANE Backbone as Ligand for Organolithium ReagentsPraz, Jezabel; Guenee, Laure; Aziz, Sarwar; Berkessel, Albrecht; Alexakis, Alexandre
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Formation of chiral fluoroalkyl products through copper-free enantioselective allylic alkylation catalyzed by an NHC ligandGrassi, David; Li, Hailing; Alexakis, Alexandre;
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Formation of Quaternary Stereogenic Centers by NHC-Cu-Catalyzed Asymmetric Conjugate Addition Reactions with Grignard Reagents on Polyconjugated Cyclic EnonesTissot, Matthieu; Poggiali, Daniele; Henon, Hélène; Mueller, Daniel; ... Alexakis, Alexandre
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Furanoside phosphite–phosphoroamidite and diphosphoroamidite ligands applied to asymmetric Cu-catalyzed allylic substitution reactionsMagre, Marc; Mazuela, Javier; Diéguez, Montserrat; Pàmies, Oscar; Alexakis, Alexandre
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Mechanistic identification and improvement of a direct enantioconvergent transformation in copper-catalyzed asymmetric allylic alkylationLanglois, Jean-Baptiste; Emery, Daniel; Mareda, Jiri; Alexakis, Alexandre;
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N-Heterocyclic Carbene-Catalyzed Annulation of α-Cyano-1,4-diketones with YnalsRomanov Michailidis, Fedor; Besnard, Céline; Alexakis, Alexandre;
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Rhodium and copper-catalyzed asymmetric conjugate addition of alkenyl nucleophilesMueller, Daniel; Alexakis, Alexandre;
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Significant Asymmetric Amplification in Enantioselective Cu/DiPPAM-catalyzed 1,6- and 1,4-Conjugate Additions of Diethylzinc to (Di)enonesMagrez, Magaly; Wencel-Delord, Joanna; Alexakis, Alexandre; Crévisy, Christophe; Mauduit, Marc

Book Chapters

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Copper-catalyzed Enantioselective Allylic SubstitutionLanglois, Jean-Baptiste; Alexakis, Alexandre;

Thesis supervisions

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Copper catalyzed conjugate addition of alkenylaluminums to unactivated substratesMueller, Daniel;
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Copper catalyzed conjugate addition to polyconjugated Michael acceptorsTissot, Matthieu;
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Enantioselective copper-catalyzed conjugate addition to sensitive Michael acceptors and application to natural product synthesis use in perfumes and flavours chemistryGremaud, Ludovic;
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Stereoselective syntesis of chiral amine building blocks from naturally occurring amino acids and application of proline derivatives on organocatalytic cyclizationsPezzati, Bernardo;

2011

Scientific Articles

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1,2-Sulfone rearrangement in organocatalytic reactionsQuintard, Adrien; Alexakis, Alexandre;
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Access to High Levels of Molecular Complexity by One-Pot Iridium/Enamine Asymmetric CatalysisQuintard, Adrien; Alexakis, Alexandre; Mazet, Clement;
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Asymmetric Organocatalytic 1,6-Conjugate Addition of Aldehydes to Dienic SulfonesMurphy, John J.; Quintard, Adrien; McArdle, Patrick; Alexakis, Alexandre; Stephens, John C.
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Conformationally Stabilized Catalysts by Fluorine Insertion: Tool for Enantioselectivity ImprovementQuintard, Adrien; Langlois, Jean-Baptiste; Emery, Daniel; Mareda, Jiri; ... Alexakis, Alexandre
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Highly Enantioselective and Regioselective Copper-Catalyzed 1,4 Addition of Grignard Reagents to Cyclic EnynonesTissot, Matthieu; Perez Hernandez, Alexandra; Müller, Daniel; Mauduit, Marc; Alexakis, Alexandre
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Highly Enantioselective Direct Vinylogous Michael Addition of γ-Butenolide to EnalsQuintard, Adrien; Lefranc, Alice; Alexakis, Alexandre;
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Highly enantioselective organocascade intermolecular iminium/enamine Michael addition on enalsQuintard, Adrien; Alexakis, Alexandre;
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Identification of a Valuable Kinetic Process in Copper-Catalyzed Asymmetric Allylic AlkylationLanglois, Jean-Baptiste; Alexakis, Alexandre;
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New Experimental Conditions for Tandem hydroalumination/Cu-Catalyzed Asymmetric Conjugate Additions to β-Substituted Cyclic EnonesMueller, Daniel; Tissot, Matthieu; Alexakis, Alexandre;

Thesis supervisions

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Development of new highly efficient amino-organocatalysts and of related methodologiesQuintard, Adrien;
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From enantioconvergent to stereodivergent processes in copper-catalyzed asymmetric allylic alkylationLanglois, Jean-Baptiste;

2010

Scientific Articles

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Aminal-pyrrolidine organocatalysts - Highly efficient and modular catalysts for α-functionalization of carbonyl compoundsQuintard, Adrien; Belot, Sébastien; Marchal, Estelle; Alexakis, Alexandre;
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Asymmetric addition of α-hetero-disubstituted aldehydes to vinyl sulfones; formation of highly functionalized tetrasubstituted carbon centresQuintard, Adrien; Alexakis, Alexandre;
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Catalytic Asymmetric Bromine-Lithium Exchange: A New Tool to Build Axial ChiralityPerron, Quentin; Alexakis, Alexandre;
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Copper-catalysed kinetic resolution of cyclic alkenyl cyclopropane malonates with organoaluminium and Grignard reagentsLadjel, Chehla; Fuchs, Nicolas; Gremaud, Ludovic; Alexakis, Alexandre;
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Copper-Catalysed Ring Opening of Polycyclic meso-Hydrazines with Trialkylaluminium Reagents and SimplePhos LigandsPalais, Laetitia; Bournaud, Chloée; Micouin, Laurent; Alexakis, Alexandre;
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Copper-catalyzed asymmetric allylic alkylation of racemic cyclic substrates: application of dynamic kinetic asymmetric transformation (DYKAT)Langlois, Jean-Baptiste; Alexakis, Alexandre;
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Copper-catalyzed enantioselective 1,4-addition to α,β-unsaturated aldehydesPalais, Laëtitia; Babel, Lucille; Quintard, Adrien; Belot, Sébastien; Alexakis, Alexandre
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Copper-free asymmetric allylic alkylation with grignard reagentsJackowski, Olivier; Alexakis, Alexandre;
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Creation of Quaternary Stereogenic Centers via Copper-Catalyzed Asymmetric Conjugate Addition of Alkenyl Alanes to α,β-Unsaturated Cyclic KetonesMüller, Daniel; Hawner, Christine; Tissot, Matthieu; Palais, Laetitia; Alexakis, Alexandre
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Enantioselective 1,6-Conjugate Addition to Cyclic Dienones Catalyzed by the Cu−DiPPAM ComplexWencel-Delord, Joanna; Alexakis, Alexandre; Crévisy, Christophe; Mauduit, Marc;
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Enantioselective and Regiodivergent Copper-Catalyzed Conjugate Addition of Trialkylaluminium Reagents to Extended Nitro-Michael AcceptorsTissot, Matthieu; Müller, Daniel; Belot, Sébastien; Alexakis, Alexandre;
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Fine-tunable monodentate phosphoroamidite and aminophosphine ligands for Rh-catalyzed asymmetric hydroformylationMazuela, Javier; Pàmies, Oscar; Diéguez, Montserrat; Palais, Laetitia; ... Alexakis, Alexandre
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Formation of Quaternary Chiral Centers by N-Heterocyclic Carbene-Cu-Catalyzed Asymmetric Conjugate Addition Reactions with Grignard Reagents on Trisubstituted Cyclic EnonesKehrli, Stefan; Martin, David; Rix, Diane; Mauduit, Marc; Alexakis, Alexandre
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Highly Enantioselective One-Pot Copper-Catalyzed 1,4 Addition/Organocatalyzed α-Substitution of EnalsQuintard, Adrien; Alexakis, Alexandre;
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Metal-catalyzed asymmetric conjugate addition reaction: formation of quaternary stereocentersHawner, Christine; Alexakis, Alexandre;
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Organocatalyst-mediated enantioselective intramolecular Michael addition of aldehydes to vinyl sulfonesBournaud, Chloée; Marchal, Estelle; Quintard, Adrien; Sulzer Mossé, Sarah; Alexakis, Alexandre
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Organocatalyzed conjugate addition of carbonyl compounds to Nitrodienes/Nitroenynes and synthetic applicationsBelot, Sébastien; Quintard, Adrien; Krause, Norbert; Alexakis, Alexandre;
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Rhodium-Catalyzed Asymmetric 1,4-Addition of Aryl Alanes to Trisubstituted Enones: Binap as an Effective Ligand in the Formation of Quaternary StereocentersHawner, Christine; Müller, Daniel; Gremaud, Ludovic; Felouat, Abdellah; ... Alexakis, Alexandre
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Tandem reactions with chiral enolates: preparation of allylic alcohols via trapping with vinyl oxiranesWelker, Matthias; Woodward, Simon; Alexakis, Alexandre;
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ω-ethylenic allylic substrates as alternatives to cyclic substrates in copper- and iridium-catalyzed asymmetric allylic alkylationGiacomina, Francesca; Riat, David; Alexakis, Alexandre;

Thesis supervisions

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Construction of enantioenriched cyclic compounds via asymmetric allylic alkylation and ring closing metathesisGiacomina, Francesca;
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Développement de nouvelles réactions, diamine ou métaux de transition, une histoire de complémentaritéPerron, Quentin;
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Enantioselective Organocatalyzed Conjugate Addition of Carbonyl Compounds to New Functionalized Nitroolefins and Applications in Gold-Catalyzed ReactionsBelot, Sébastien;
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