Alexakis, Alexandre

 
 
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2014

Scientific Articles

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Asymmetric Conjugate Addition to α-Substituted Enones/Enolate TrappingGermain, Nicolas; Guenee, Laure; Mauduit, Marc; Alexakis, Alexandre;
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Construction of Bicyclo[3.2.1]octanes with Four Stereogenic Centers by Organocatalytic Domino Michael/Aldol ReactionLefranc, Alice; Gremaud, Ludovic; Alexakis, Alexandre;
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Copper-Catalyzed Propargylic Substitution of Dichloro Substrates: Enantioselective Synthesis of Trisubstituted Allenes and Formation of Propargylic Quaternary Stereogenic CentersLi, Hailing; Grassi, David; Guenee, Laure; Buergi, Thomas; Alexakis, Alexandre
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Direct Organocatalytic Construction of Bicyclo[3.2.1]octanes by Domino Michael/Aldol Reaction with β,γ-Unsaturated 1,2-Keto AmidesLefranc, Alice; Guenee, Laure; Contal, Sylvie; Alexakis, Alexandre;
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Domino Asymmetric Conjugate Addition–Conjugate AdditionGermain, Nicolas; Schlaefli, Dorian; Chellat, Mathieu; Rosset, Stéphane; Alexakis, Alexandre
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Enantioselective 1,4-additions of ClMeAl(CH=CHR) (R = alkyl, alkenyl, Ph) to cyclohexenonesWillcox, Darren; Woodward, Simon; Alexakis, Alexandre;
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Enantioselective Catalytic Fluorinative Aza-semipinacol RearrangementRomanov Michailidis, Fedor; Pupier, Marion; Besnard, Céline; Buergi, Thomas; Alexakis, Alexandre
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Enantioselective halogenative semi-pinacol rearrangement: a stereodivergent reaction on a racemic mixtureRomanov Michailidis, Fedor; Pupier, Marion; Guenee, Laure; Alexakis, Alexandre;
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Transition metal-free asymmetric and diastereoselective allylic alkylation using Grignard reagents: construction of vicinal stereogenic centers via kinetic resolutionGrassi, David; Alexakis, Alexandre;

Edited Books

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Copper-Catalyzed Asymmetric SynthesisAlexakis, Alexandre; Krause, Norbert; Woodward, Simon;

Book Chapters

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Copper-Catalyzed Asymmetric Conjugate AdditionAlexakis, Alexandre; Krause, Norbert; Woodward, Simon;
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Copper-Catalyzed Asymmetric Conjugate Addition and Allylic Substitution of Organometallic Reagents to Extended Multiple-Bond SystemsTissot, Matthieu; Li, Hailing; Alexakis, Alexandre;

Thesis supervisions

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Applications of the asymmetric bromine-lithium exchange to the synthesis of natural product and diphosphinesGraff, Julien;
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Copper-catalyzed asymmetric conjugate addition of alkenyl- and alkylalanes to α,β-unsaturated lactams: enantioselective total synthesis of Riccardiphenol BCottet, Pierre;
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Copper-Catalyzed asymmetric conjugate additions of Grignard reagents and electrophilic trappings of Mg-enolatesGermain, Nicolas;
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Enantioselective reactions with N-heterocyclic carbene and phosphoric acid catalysts: importance of cationic intermediatesRomanov Michailidis, Fedor;
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New substrates for the copper-catalyzed enantioselective allylic and propargylic substitutionsLi, Hailing;
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Organocatalytic enantioselective construction of mono- and polycyclic structures by domino reactionsLefranc, Alice;
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Transition metal-free Asymmetric Allylic Alkylation using Grignard reagents: design of ligand, mechanistic investigations, substrates scope and applicationsGrassi, David;

2013

Scientific Articles

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Asymmetric Bromine–Lithium Exchange: Application toward the Synthesis of Natural ProductGraff, Julien; Debande, Thibaut; Praz, Jezabel; Guenee, Laure; Alexakis, Alexandre
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Construction of Enantioenriched Cyclic Compounds by Asymmetric Allylic Alkylation and Ring-Closing MetathesisGiacomina, Francesca; Alexakis, Alexandre;
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Copper-Catalyzed Asymmetric Conjugate Addition of Alkenyl- and Alkylalanes to α,β-Unsaturated LactamsCottet, Pierre; Mueller, Daniel; Alexakis, Alexandre;
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Copper-Free Asymmetric Allylic Alkylation of Trisubstituted Cyclic Allyl Bromides Using Grignard ReagentsGrassi, David; Alexakis, Alexandre;
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Copper-Free Asymmetric Allylic Alkylation with a Grignard Reagent: Design of the Ligand and Mechanistic StudiesGrassi, David; Dolka, Chrysanthi; Jackowski, Olivier; Alexakis, Alexandre;
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Creation of Highly Congested Quaternary Centers via Cu-catalyzed Conjugate Addition of Alkenyl Alanates to β-Substituted Cyclic EnonesMueller, Daniel; Alexakis, Alexandre;
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Direct Trapping of Sterically Encumbered Aluminum EnolatesBleschke, Christian Alexander; Tissot, Matthieu; Mueller, Daniel; Alexakis, Alexandre;
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Enantio- and Regioselective Conjugate Addition of Organometallic Reagents to Linear Polyconjugated NitroolefinsTissot, Matthieu; Alexakis, Alexandre;
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Enantioselective 1,6-Conjugate Addition of Dialkylzinc Reagents to Acyclic Dienones Catalyzed by Cu-DiPPAM Complex-Extension to Asymmetric Sequential 1,6/1,4-Conjugate AdditionMagrez-Chiquet, Magaly; Morin, Marie S. T.; Wencel-Delord, Joanna; Drissi Amraoui, Sammy; ... Mauduit, Marc
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Enantioselective Copper-Catalyzed Conjugate Addition of Trimethylaluminum to β,γ-Unsaturated α-Ketoamides: Efficient Access to γ-Methyl-Substituted Carbonyl CompoundsContal, Sylvie; Gremaud, Ludovic; Alexakis, Alexandre;
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Enantioselective Organocatalytic Fluorination-Induced Wagner-Meerwein RearrangementRomanov Michailidis, Fedor; Guenee, Laure; Alexakis, Alexandre;
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Enantioselective Organocatalytic Iodination-Initiated Wagner–Meerwein RearrangementRomanov Michailidis, Fedor; Guenee, Laure; Alexakis, Alexandre;
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Formation of Quaternary Stereogenic Centers by Copper-Catalyzed Asymmetric Conjugate Addition Reactions of Alkenylaluminums to Trisubstituted EnonesMueller, Daniel; Alexakis, Alexandre;
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Highly Diastereo- and Enantioselective Organocatalytic Domino Michael/Aldol Reaction of Acyclic 3-Halogeno-1,2-Diones to α,β-Unsaturated AldehydesLefranc, Alice; Guenee, Laure; Alexakis, Alexandre;
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Organocatalytic Asymmetric Annulation of 1,3-Bis(alkoxycarbonyl)buta-1,3-dienes and AldehydesPezzati, Bernardo; Chellat, Mathieu; Murphy, John J.; Besnard, Céline; ... Alexakis, Alexandre
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Practical Synthesis of SimplePhos Ligands: Further Development of Alkyl-Substituted PhosphanaminesMueller, Daniel; Guenee, Laure; Alexakis, Alexandre;

Book Chapters

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Organocatalytic conjugate addition in stereoselective synthesisQuintard, Adrien; Alexakis, Alexandre;

Thesis supervisions

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Design of new chiral diamines as efficient ligands for organolithium reagents in asymmetric synthesisPraz, Jezabel;
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