Allylic organobismetallic reagents - Part 1

Normant, Jean F.; Quirion, J.Ch.; Alexakis, Alexandre; Masuda, Y.

doi:10.1016/S0040-4039(00)99293-1

Scientific article

Letter

English

Allylic organobismetallic reagents - Part 1

ContributorsNormant, Jean F.; Quirion, J.Ch.; Alexakis, Alexandre; Masuda, Y.

Published inTetrahedron letters, vol. 30, no. 30, p. 3955-3958

Publication date1989

Abstract

Allyl-allenyl zinc reagents undergo a rearrangement leading to allylic bis metallic species. A high regioselectivity is observed when these reagents are treated with a variety of electrophiles. The net result is an access to highly functionalized vinyl zinc reagents.

Affiliation entities

Not a UNIGE publication

Citation (ISO format)

NORMANT, Jean F. et al. Allylic organobismetallic reagents - Part 1. In: Tetrahedron letters, 1989, vol. 30, n° 30, p. 3955–3958. doi: 10.1016/S0040-4039(00)99293-1

Article (Published version)

Identifiers

PID : unige:8211
DOI : 10.1016/S0040-4039(00)99293-1

Journal ISSN0040-4039

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Allylic organobismetallic reagents - Part 1

Allyl-allenyl zinc reagents undergo a rearrangement leading to allylic bis metallic species. A high regioselectivity is observed when these reagents are treated with a variety of electrophiles. The net result is an access to highly functionalized vinyl zinc reagents.

Technical informations