Two-step synthesis of homochiral monoaminals of tricarbonylphthalaldehydechromium complex

Rose-Munch, Françoise; Gagliardini, Vanessa; Perrotey, Anne; Tranchier, Jean-Philippe; Rose, Eric; Mangeney, Pierre; Alexakis, Alexandre; Kanger, Tonis; Vaissermann, Jacqueline

doi:10.1039/a906043j

Scientific article

English

Two-step synthesis of homochiral monoaminals of tricarbonylphthalaldehydechromium complex

ContributorsRose-Munch, Françoise; Gagliardini, Vanessa; Perrotey, Anne; Tranchier, Jean-Philippe; Rose, Eric; Mangeney, Pierre; Alexakis, Alexandre; Kanger, Tonis; Vaissermann, Jacqueline

Published inChemical communications, vol. 34, no. 20, p. 2061-2062

Publication date1999

Abstract

Tricarbonylphthalaldehydechromium complex can be prepared using a one pot procedure starting from tricarbonylbenzenechromium: the protection of one aldehyde function by chiral diamines leads to the formation of two diastereoisomers of the monoaminal of the phthlaldehyde complexes, efficient precursors of enantiopure ortho-substituted alkenyl arene complexes.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

ROSE-MUNCH, Françoise et al. Two-step synthesis of homochiral monoaminals of tricarbonylphthalaldehydechromium complex. In: Chemical communications, 1999, vol. 34, n° 20, p. 2061–2062. doi: 10.1039/a906043j

Article (Published version)

Identifiers

PID : unige:8162
DOI : 10.1039/a906043j

Journal ISSN1359-7345

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Two-step synthesis of homochiral monoaminals of tricarbonylphthalaldehydechromium complex

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