en
Scientific article
Letter
English

First diastereoselective asymmetric carbometallation of chiral vinyl metals

Published inTetrahedron letters, vol. 39, no. 27, p. 4821-4824
Publication date1998
Abstract

Addition of substituted allylzinc reagents to chiral (Z) metallated allyl amines (or aminal) bearing a chiral aromatic moiety is face selective, and delivers ß-methylated amines with good diastereomeric excess.

Affiliation Not a UNIGE publication
Citation (ISO format)
BRASSEUR, Denis et al. First diastereoselective asymmetric carbometallation of chiral vinyl metals. In: Tetrahedron letters, 1998, vol. 39, n° 27, p. 4821–4824. doi: 10.1016/S0040-4039(98)00942-3
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Article (Published version)
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ISSN of the journal0040-4039
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