γ-Tributylstannyl-β-metallated acrolein : a versatile synthon

Marek, Ilane; Alexakis, Alexandre; Normant, Jean F.

doi:10.1016/0040-4039(91)80163-Z

Scientific article

Letter

English

γ-Tributylstannyl-β-metallated acrolein : a versatile synthon

ContributorsMarek, Ilane; Alexakis, Alexandre; Normant, Jean F.

Published inTetrahedron letters, vol. 32, no. 44, p. 6337-6340

Publication date1991

Abstract

The stannocupration of the diethoxypropyne affords very selectively the title compound which can be alkylated with various electrophiles.

Keywords

stannocupration
d2
d3 acrolein equivalent
diethoxypropyne
vinyl tin

Affiliation entities

Not a UNIGE publication

Citation (ISO format)

MAREK, Ilane, ALEXAKIS, Alexandre, NORMANT, Jean F. γ-Tributylstannyl-β-metallated acrolein : a versatile synthon. In: Tetrahedron letters, 1991, vol. 32, n° 44, p. 6337–6340. doi: 10.1016/0040-4039(91)80163-Z

Article (Published version)

Identifiers

PID : unige:8083
DOI : 10.1016/0040-4039(91)80163-Z

Journal ISSN0040-4039

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γ-Tributylstannyl-β-metallated acrolein : a versatile synthon

The stannocupration of the diethoxypropyne affords very selectively the title compound which can be alkylated with various electrophiles.

Technical informations