Catalytic enantioselective deprotonation of meso-epoxides utilising homochiral bis-lithium amide bases

Tierney, Jason P.; Alexakis, Alexandre; Mangeney, Pierre

doi:10.1016/S0957-4166(97)00084-0

Scientific article

English

Catalytic enantioselective deprotonation of meso-epoxides utilising homochiral bis-lithium amide bases

ContributorsTierney, Jason P.; Alexakis, Alexandre; Mangeney, Pierre

Published inTetrahedron: asymmetry, vol. 8, no. 7, p. 1019-1022

Publication date1997

Abstract

(R)-2-Cyclohexen-1-ol and (R)-2-cyclooctene-1-ol have been prepared in very good ee using R,R-homochiral bis-lithium amide bases derived from homochiral C2 symmetric diamines. (R)-2-Cyclohexen-1-ol has been synthesized in good ee utilising catalytic homochiral bis-lithium amide in the presence of n-butyl lithium.

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Citation (ISO format)

TIERNEY, Jason P., ALEXAKIS, Alexandre, MANGENEY, Pierre. Catalytic enantioselective deprotonation of meso-epoxides utilising homochiral bis-lithium amide bases. In: Tetrahedron: asymmetry, 1997, vol. 8, n° 7, p. 1019–1022. doi: 10.1016/S0957-4166(97)00084-0

Article (Published version)

Identifiers

PID : unige:8060
DOI : 10.1016/S0957-4166(97)00084-0

Journal ISSN0957-4166

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Catalytic enantioselective deprotonation of meso-epoxides utilising homochiral bis-lithium amide bases

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