Asymmetric cleavage of chiral α,β-ethylenic acetals by organolithium reagents

Alexakis, Alexandre; Mhamdi, Farida; Lagasse, Franz; Mangeney, Pierre

doi:10.1016/S0957-4166(96)00438-7

Article scientifique

Anglais

Asymmetric cleavage of chiral α,β-ethylenic acetals by organolithium reagents

Contributeurs/tricesAlexakis, Alexandre; Mhamdi, Farida; Lagasse, Franz; Mangeney, Pierre

Publié dansTetrahedron: asymmetry, vol. 7, no. 12, p. 3343-3346

Date de publication1996

Résumé

a,ß-Ethylenic chiral acetals react regio- and stereoselectively with organolithium reagents. The obtained enol ether may be hydrolyzed into a chiral ß-disubstituted aldehyde.

Structure d'affiliation Pas une publication de l'UNIGE

Citation (format ISO)

ALEXAKIS, Alexandre et al. Asymmetric cleavage of chiral α,β-ethylenic acetals by organolithium reagents. In: Tetrahedron: asymmetry, 1996, vol. 7, n° 12, p. 3343–3346. doi: 10.1016/S0957-4166(96)00438-7

Article (Published version)

Identifiants

PID : unige:8057
DOI : 10.1016/S0957-4166(96)00438-7

ISSN du journal0957-4166

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Création21/06/2010 14:15:56

Première validation21/06/2010 14:15:56

Heure de mise à jour14/03/2023 15:47:53

Changement de statut14/03/2023 15:47:53

Dernière indexation15/01/2024 20:26:29

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Asymmetric cleavage of chiral α,β-ethylenic acetals by organolithium reagents

a,ß-Ethylenic chiral acetals react regio- and stereoselectively with organolithium reagents. The obtained enol ether may be hydrolyzed into a chiral ß-disubstituted aldehyde.

Informations techniques