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Scientific article
English

A highly effective phosphoramidite ligand for asymmetric allylic substitution

Published inAngewandte Chemie, vol. 43, no. 18, p. 2426-2428
Publication date2004
Abstract

Very high enantioselectivity has been achieved both in the copper-catalyzed alkylation of allylic substrates by Grignard and organozinc reagents and in the iridium-catalyzed amination of cinnamyl carbonate by employing a very efficient phosphoramidite ligand

Keywords
  • Allylation
  • Asymmetric catalysis
  • Chiral auxiliaries
  • Copper
  • Iridium
  • Magnesium
Citation (ISO format)
TISSOT-CROSET, Karine, POLET, Damien, ALEXAKIS, Alexandre. A highly effective phosphoramidite ligand for asymmetric allylic substitution. In: Angewandte Chemie, 2004, vol. 43, n° 18, p. 2426–2428. doi: 10.1002/anie.200353744
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Article (Published version)
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Identifiers
ISSN of the journal1433-7851
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