Highly enantioselective copper(I)-phosphoramidite-catalysed additions of organoaluminium reagents to enones

Alexakis, Alexandre; Albrow, Victoria; Biswas, Kallolmay; Vuagnoux-D'Augustin De, Magali; Prieto, Oscar; Woodward, Simon

doi:10.1039/b503074a

Scientific article

English

Highly enantioselective copper(I)-phosphoramidite-catalysed additions of organoaluminium reagents to enones

ContributorsAlexakis, Alexandre; Albrow, Victoria; Biswas, Kallolmay; Vuagnoux-D'Augustin De, Magali; Prieto, Oscar; Woodward, Simon

Published inChemical communications, vol. 40, no. 22, p. 2843-2845

Publication date2005

Abstract

Simple phosphoramidite ligands afford good to excellent levels of enantioselectivity in 1,4-additions of AlR3 species to enones; sequential carboalumination-ACA cascades are possible.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

ALEXAKIS, Alexandre et al. Highly enantioselective copper(I)-phosphoramidite-catalysed additions of organoaluminium reagents to enones. In: Chemical communications, 2005, vol. 40, n° 22, p. 2843–2845. doi: 10.1039/b503074a

Article (Published version)

Identifiers

PID : unige:8044
DOI : 10.1039/b503074a
PMID : 15928777

Journal ISSN1359-7345

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Highly enantioselective copper(I)-phosphoramidite-catalysed additions of organoaluminium reagents to enones

Simple phosphoramidite ligands afford good to excellent levels of enantioselectivity in 1,4-additions of AlR3 species to enones; sequential carboalumination-ACA cascades are possible.

Technical informations