Efficient Synthesis of Tris(acetonitrile)-(η5-cyclopentadienyl)-ruthenium(II) Hexafluorophosphate via Ruthenocene

Kundig, Ernst Peter; Monnier, F.R.

doi:10.1002/adsc.200404124

Scientific article

English

Efficient Synthesis of Tris(acetonitrile)-(η5-cyclopentadienyl)-ruthenium(II) Hexafluorophosphate via Ruthenocene

ContributorsKundig, Ernst Peter; Monnier, F.R.

Published inAdvanced synthesis & catalysis, vol. 346, no. 8, p. 901-904

Publication date2004

Abstract

[Ru(η5-C5H5)(CH3CN)3][PF6] (1), a versatile precursor to catalysts containing the CpRu+ complex fragment, can be obtained in high yield via Cp/naphthalene exchange in ruthenocene. This new route via the complex [RuCp(naphthalene)][PF6] (4) avoids both highly toxic thallium reagents and the need for a photoreactor.

Keywords

Arene complexes
Cyclopentadienyl ligands
Ligand exchange
Ruthenium
Ruthenocene

NoteSpecial Issue : Dedicated Cluster: Dedicated to Prof. Dr. J. Bargon on the occasion of his 65th birthday

Affiliation

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

KUNDIG, Ernst Peter, MONNIER, F.R. Efficient Synthesis of Tris(acetonitrile)-(η5-cyclopentadienyl)-ruthenium(II) Hexafluorophosphate via Ruthenocene. In: Advanced synthesis & catalysis, 2004, vol. 346, n° 8, p. 901–904. doi: 10.1002/adsc.200404124

Article

Identifiers

PID : unige:7887
DOI : 10.1002/adsc.200404124

ISSN of the journal1615-4150

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Efficient Synthesis of Tris(acetonitrile)-(η5-cyclopentadienyl)-ruthenium(II) Hexafluorophosphate via Ruthenocene

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