ChemInform Abstract: A Mild and Efficient CH<sub>2</sub>-Extrusion Reaction for the Enantiospecific Synthesis of Highly Configurationally Stable Troeger Bases

Pujari, Sandip; Besnard, Céline; Buergi, Thomas; Lacour, Jérôme

doi:10.1002/chin.201543111

Article scientifique

Français

ChemInform Abstract: A Mild and Efficient CH₂-Extrusion Reaction for the Enantiospecific Synthesis of Highly Configurationally Stable Troeger Bases

Contributeurs/tricesPujari, Sandip; Besnard, Céline; Buergi, Thomas; Lacour, Jérôme

Publié dansChem Inform, vol. 46, no. 43

Date de publication2015

Résumé

Oxidation of ethano-Troeger bases (I) and (III) with DDQ in wet nitromethane results in a highly enantiospecific methylene extrusion to afford ring contracted products (II) and (IV) which are significantly more configurationally stable than regular Troeger bases.

Mots-clés

Bridged compounds (heterocyclic compounds)
Ring contraction

Structure d'affiliation

Groupe de recherche

Citation (format ISO)

PUJARI, Sandip et al. ChemInform Abstract: A Mild and Efficient CH<sub>2</sub>-Extrusion Reaction for the Enantiospecific Synthesis of Highly Configurationally Stable Troeger Bases. In: Chem Inform, 2015, vol. 46, n° 43. doi: 10.1002/chin.201543111

Identifiants

PID : unige:76521
DOI : 10.1002/chin.201543111

ISSN du journal0931-7597

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Création16/10/2015 14:35:00

Première validation16/10/2015 14:35:00

Heure de mise à jour14/03/2023 23:45:46

Changement de statut14/03/2023 23:45:46

Dernière indexation16/01/2024 19:18:47

Archive ouverte UNIGE

ChemInform Abstract: A Mild and Efficient CH2-Extrusion Reaction for the Enantiospecific Synthesis of Highly Configurationally Stable Troeger Bases

Oxidation of ethano-Troeger bases (I) and (III) with DDQ in wet nitromethane results in a highly enantiospecific methylene extrusion to afford ring contracted products (II) and (IV) which are significantly more configurationally stable than regular Troeger bases.

Informations techniques

ChemInform Abstract: A Mild and Efficient CH₂-Extrusion Reaction for the Enantiospecific Synthesis of Highly Configurationally Stable Troeger Bases