Supramolecular Stereocontrol of Octahedral Metal-Centered Chirality. Ligand Modulation

Jodry, Jonathan; Frantz, Richard; Lacour, Jérôme

doi:10.1021/ic049661d

Scientific article

English

Supramolecular Stereocontrol of Octahedral Metal-Centered Chirality. Ligand Modulation

ContributorsJodry, Jonathan; Frantz, Richard; Lacour, Jérôme

Published inInorganic chemistry, vol. 43, p. 3329-3331

Publication date2004

Abstract

By associating chiral labile [FeL3](2+) complexes with TRISPHAT anions, a stereocontrol of the metal-centered chirality is feasible; the sense of the stereoselective induction and its magnitude strongly depends upon the structure of the diimine ligands (L: bpy, phen).

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

JODRY, Jonathan, FRANTZ, Richard, LACOUR, Jérôme. Supramolecular Stereocontrol of Octahedral Metal-Centered Chirality. Ligand Modulation. In: Inorganic chemistry, 2004, vol. 43, p. 3329–3331. doi: 10.1021/ic049661d

Article

Identifiers

PID : unige:7018
DOI : 10.1021/ic049661d
PMID : 15154791

Journal ISSN0020-1669

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Supramolecular Stereocontrol of Octahedral Metal-Centered Chirality. Ligand Modulation

By associating chiral labile [FeL3](2+) complexes with TRISPHAT anions, a stereocontrol of the metal-centered chirality is feasible; the sense of the stereoselective induction and its magnitude strongly depends upon the structure of the diimine ligands (L: bpy, phen).

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