NMR Evaluation of the Configurational Stability of Cu(I) Complexes

Desvergnes-Breuil, Valérie; Hebbe, Virginie; Dietrich-Buchecker, Christiane; Sauvage, Jean-Pierre; Lacour, Jérôme

doi:10.1021/ic0259890

Scientific article

English

NMR Evaluation of the Configurational Stability of Cu(I) Complexes

ContributorsDesvergnes-Breuil, Valérie; Hebbe, Virginie; Dietrich-Buchecker, Christiane; Sauvage, Jean-Pierre; Lacour, Jérôme

Published inInorganic chemistry, vol. 42, no. 2, p. 255-257

Publication date2003

Abstract

Association of chiral [CuL2]+ complexes (L = 2-R-phen, 6-R-bpy, and 2-iminopyridine) with TRISPHAT (tris(tetrachlorobenzenediolato)phosphate(V)) anion leads to NMR enantiodifferentiation, which can be used to determine the kinetics of racemization of the complexes.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

DESVERGNES-BREUIL, Valérie et al. NMR Evaluation of the Configurational Stability of Cu(I) Complexes. In: Inorganic chemistry, 2003, vol. 42, n° 2, p. 255–257. doi: 10.1021/ic0259890

Article

Identifiers

PID : unige:7016
DOI : 10.1021/ic0259890

Journal ISSN0020-1669

649views

0downloads

Creation18/06/2010 08:55:08

First validation18/06/2010 08:55:08

Update time14/03/2023 15:42:14

Status update14/03/2023 15:42:14

Last indexation10/06/2025 21:34:31

Archive ouverte UNIGE

NMR Evaluation of the Configurational Stability of Cu(I) Complexes

Association of chiral [CuL2]+ complexes (L = 2-R-phen, 6-R-bpy, and 2-iminopyridine) with TRISPHAT (tris(tetrachlorobenzenediolato)phosphate(V)) anion leads to NMR enantiodifferentiation, which can be used to determine the kinetics of racemization of the complexes.

Technical informations