NMR Enantiodifferentiation of Thiiranium Cations by BINPHAT and TRISPHAT Chiral Anions

Pasquato, L.; Herse, Christelle; Lacour, Jérôme

doi:10.1016/S0040-4039(02)01144-9

Scientific article

Letter

English

NMR Enantiodifferentiation of Thiiranium Cations by BINPHAT and TRISPHAT Chiral Anions

ContributorsPasquato, L.; Herse, Christelle; Lacour, Jérôme

Published inTetrahedron letters, vol. 43, no. 32, 5517

Publication date2002

Abstract

BINPHAT anion—rather than TRISPHAT—is an efficient NMR chiral shift reagent for thiiranium ions such as c-2,t-3-di-tert-butyl-r-1-methylthiiranium and t-2-tert-butyl-c-3-phenyl-r-1-methylthiiranium cations. This is the first report on the NMR enantiodifferentiation of such chiral cations. BINPHAT anion is an efficient NMR chiral shift reagent for thiiranium ions.

Keywords

NMR enantiodifferentiation
Iranium ions
Thiiranium ions
BINPHAT
TRISPHAT
Chiral anions

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

PASQUATO, L., HERSE, Christelle, LACOUR, Jérôme. NMR Enantiodifferentiation of Thiiranium Cations by BINPHAT and TRISPHAT Chiral Anions. In: Tetrahedron letters, 2002, vol. 43, n° 32, p. 5517. doi: 10.1016/S0040-4039(02)01144-9

Article

Identifiers

PID : unige:7006
DOI : 10.1016/S0040-4039(02)01144-9

Journal ISSN0040-4039

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NMR Enantiodifferentiation of Thiiranium Cations by BINPHAT and TRISPHAT Chiral Anions

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