Synthese und Trennung der Enantiomere des konfigurationsstabilen Tris(tetrachlorbenzoldiolato)phosphat(V)-Ions

Lacour, Jérôme; Ginglinger, Catherine; Grivet, Chantal; Bernardinelli, Gérald Hugues

doi:10.1002/ange.19971090628

Scientific article

German

Synthese und Trennung der Enantiomere des konfigurationsstabilen Tris(tetrachlorbenzoldiolato)phosphat(V)-Ions

ContributorsLacour, Jérôme

; Ginglinger, Catherine; Grivet, Chantal; Bernardinelli, Gérald Hugues

Published inAngewandte Chemie, vol. 109, no. 6, p. 660-662

Publication date1997

Abstract

Easily accessible and configurationally stable are words that describe the enantiopure tris(tetrachlorobenzenediolato)phosphate(V) ion (1). These qualities predetermine 1 for use in enantiomeric resolution and asymmetric synthesis. X-ray structure analysis of the cinchonidinium salt of 1 confirmed the octahedral geometry and provided the absolute configuration of the anion.

Keywords

Chirality
Cinchonidine
Enantiomeric resolution
Phosphorus

NoteParu également dans Angewandte Chemie: International Edition in English sous le titre:"Synthesis and Resolution of the Configurationally Stable Tris(tetrachlorobenzenediolato)phosphate Anion" en 1997, 37(6), 608-610

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

LACOUR, Jérôme et al. Synthese und Trennung der Enantiomere des konfigurationsstabilen Tris(tetrachlorbenzoldiolato)phosphat(V)-Ions. In: Angewandte Chemie, 1997, vol. 109, n° 6, p. 660–662. doi: 10.1002/ange.19971090628

Article

Identifiers

PID : unige:6973
DOI : 10.1002/ange.19971090628

Journal ISSN0044-8249

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Synthese und Trennung der Enantiomere des konfigurationsstabilen Tris(tetrachlorbenzoldiolato)phosphat(V)-Ions

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