Novel Heteroleptic cis-(C^N2)Pd(II) Chelates for the Preparation of Enantiopure Planar Chiral Cyclopalladated 2-[tricarbonyl(η6-phenyl)chromium]pyridine

Berger, Alexsandro; Djukic, Jean-Pierre; Pfeffer, Michel; de Cian, André; Kyritsakas-Gruber, Nathalie; Lacour, Jérôme; Vial, Laurent

doi:10.1039/b211873d

Scientific article

English

Novel Heteroleptic cis-(C^N2)Pd(II) Chelates for the Preparation of Enantiopure Planar Chiral Cyclopalladated 2-[tricarbonyl(η6-phenyl)chromium]pyridine

ContributorsBerger, Alexsandro; Djukic, Jean-Pierre; Pfeffer, Michel; de Cian, André; Kyritsakas-Gruber, Nathalie; Lacour, Jérôme

; Vial, Laurent

Published inChemical communications, vol. 38, no. 5, 658

Publication date2003

Abstract

In the presence of large amounts of [Me4N]Cl, the reaction of ortho-chloromercurated 2-[(n6-phenyl)tricarbonylchromium]pyridine with µ-chloro cyclopalladated aromatic compounds yields a series of new heteroleptic heterodinuclear cis-(C^N)2Pd(II) complexes, which are valuable precursors of planar chiral cyclopalladated (n6-arene)Cr(CO)3 complexes.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

BERGER, Alexsandro et al. Novel Heteroleptic cis-(C^N2)Pd(II) Chelates for the Preparation of Enantiopure Planar Chiral Cyclopalladated 2-[tricarbonyl(η6-phenyl)chromium]pyridine. In: Chemical communications, 2003, vol. 38, n° 5, p. 658. doi: 10.1039/b211873d

Article

Identifiers

PID : unige:6966
DOI : 10.1039/b211873d

Journal ISSN1359-7345

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Novel Heteroleptic cis-(C^N2)Pd(II) Chelates for the Preparation of Enantiopure Planar Chiral Cyclopalladated 2-[tricarbonyl(η6-phenyl)chromium]pyridine

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