Synthesis of {323}-p-Octiphenyls: Orthogonal Functionalization along a Rigid-Rod Scaffold for Refined Supramolecular Architecture

Ronan, Dawn; Baudry, Yoann Cyril; Jeannerat, Damien; Matile, Stefan

doi:10.1021/ol036363w

Scientific article

Letter

English

Synthesis of {323}-p-Octiphenyls: Orthogonal Functionalization along a Rigid-Rod Scaffold for Refined Supramolecular Architecture

ContributorsRonan, Dawn; Baudry, Yoann Cyril; Jeannerat, Damien; Matile, Stefan

Published inOrganic letters, vol. 6, no. 6, p. 885-887

Publication date2004

Abstract

The synthesis of p-octiphenyls carrying orthogonal tert-butyl esters in the peripheral positions 1(2), 2(2), 3(3), 6(2), 7(3), and 8(2) and either p-methoxybenzyl or benzyl ester substituents in the central positions 4(2) and 5(3) is described. Resolution-enhanced HSQC/HMBC two-dimensional NMR spectroscopy is implemented as an attractive method for the complete characterization of complex p-oligophenyl scaffolds.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

RONAN, Dawn et al. Synthesis of {323}-p-Octiphenyls: Orthogonal Functionalization along a Rigid-Rod Scaffold for Refined Supramolecular Architecture. In: Organic letters, 2004, vol. 6, n° 6, p. 885–887. doi: 10.1021/ol036363w

Article

Identifiers

PID : unige:6962
DOI : 10.1021/ol036363w
PMID : 15012056

Journal ISSN1523-7052

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Synthesis of {323}-p-Octiphenyls: Orthogonal Functionalization along a Rigid-Rod Scaffold for Refined Supramolecular Architecture

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