Configurational Ordering of Cationic Chiral Dyes Using a Novel C2-symmetric Hexacoordinated Phosphate Anion

Lacour, Jérôme; Londez, Anne Laurence; Goujon-Ginglinger, Catherine; Buss, Volker; Bernardinelli, Gérald Hugues

doi:10.1021/ol006731l

Scientific article

English

Configurational Ordering of Cationic Chiral Dyes Using a Novel C2-symmetric Hexacoordinated Phosphate Anion

ContributorsLacour, Jérôme

; Londez, Anne Laurence; Goujon-Ginglinger, Catherine; Buss, Volker; Bernardinelli, Gérald Hugues

Published inOrganic letters, vol. 2, no. 26, p. 4185-4188

Publication date2000

Abstract

C(2)-Symmetry hexacoordinated phosphorus BINPHAT anion-of configuration controlled by a BINOL ligand-can be prepared readily in a one-pot process and behaves as an efficient NMR chiral shift agent and chiral inducer onto monomethinium dyes (CD, (1)H NMR).

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

LACOUR, Jérôme et al. Configurational Ordering of Cationic Chiral Dyes Using a Novel C2-symmetric Hexacoordinated Phosphate Anion. In: Organic letters, 2000, vol. 2, n° 26, p. 4185–4188. doi: 10.1021/ol006731l

Article (Published version)

Identifiers

PID : unige:6955
DOI : 10.1021/ol006731l
PMID : 11150195

Journal ISSN1523-7052

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Configurational Ordering of Cationic Chiral Dyes Using a Novel C2-symmetric Hexacoordinated Phosphate Anion

C(2)-Symmetry hexacoordinated phosphorus BINPHAT anion-of configuration controlled by a BINOL ligand-can be prepared readily in a one-pot process and behaves as an efficient NMR chiral shift agent and chiral inducer onto monomethinium dyes (CD, (1)H NMR).

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